Small Size Rh Nanoparticles in Micelle Nanostructure by Ionic Liquid/CTAB for Acceptorless Dehydrogenation of Alcohols Only in Pure Water

Lin Yao; Jun Zhao; Jong Min Lee

doi:10.1021/acssuschemeng.6b02994

Small Size Rh Nanoparticles in Micelle Nanostructure by Ionic Liquid/CTAB for Acceptorless Dehydrogenation of Alcohols Only in Pure Water

Lin Yao, Jun Zhao, Jong Min Lee^*

^*Corresponding author for this work

Department of Biology

Research output: Contribution to journal › Journal article › peer-review

16 Citations (Scopus)

Abstract

Ultrasmall size Rh nanoparticles were synthesized and stabilized by the complex of cetyltrimethylammonium bromide and water-soluble ionic liquid molecules. The new catalytic system shows excellent catalytic activity in the oxidation of alcohols to aldehydes or ketones only in pure water through acceptorless dehydrogenation. It is atom economic, clean and green in the synthesis of aldehydes or ketones and H₂ production at the same time.

Original language	English
Pages (from-to)	2056-2060
Number of pages	5
Journal	ACS Sustainable Chemistry and Engineering
Volume	5
Issue number	3
DOIs	https://doi.org/10.1021/acssuschemeng.6b02994
Publication status	Published - 6 Mar 2017

Scopus Subject Areas

General Chemistry
Environmental Chemistry
General Chemical Engineering
Renewable Energy, Sustainability and the Environment

User-Defined Keywords

Catalyst
Ionic liquid
Nanoparticle
Rhodium
Water

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acssuschemeng.6b02994

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title = "Small Size Rh Nanoparticles in Micelle Nanostructure by Ionic Liquid/CTAB for Acceptorless Dehydrogenation of Alcohols Only in Pure Water",

abstract = "Ultrasmall size Rh nanoparticles were synthesized and stabilized by the complex of cetyltrimethylammonium bromide and water-soluble ionic liquid molecules. The new catalytic system shows excellent catalytic activity in the oxidation of alcohols to aldehydes or ketones only in pure water through acceptorless dehydrogenation. It is atom economic, clean and green in the synthesis of aldehydes or ketones and H2 production at the same time.",

keywords = "Catalyst, Ionic liquid, Nanoparticle, Rhodium, Water",

author = "Lin Yao and Jun Zhao and Lee, {Jong Min}",

note = "Funding information: This work was supported by Academic Research Fund (RGT27/13) of Ministry of Education in Singapore. Publisher Copyright: {\textcopyright} 2017 American Chemical Society",

year = "2017",

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doi = "10.1021/acssuschemeng.6b02994",

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AU - Yao, Lin

AU - Zhao, Jun

AU - Lee, Jong Min

PY - 2017/3/6

Y1 - 2017/3/6

N2 - Ultrasmall size Rh nanoparticles were synthesized and stabilized by the complex of cetyltrimethylammonium bromide and water-soluble ionic liquid molecules. The new catalytic system shows excellent catalytic activity in the oxidation of alcohols to aldehydes or ketones only in pure water through acceptorless dehydrogenation. It is atom economic, clean and green in the synthesis of aldehydes or ketones and H2 production at the same time.

AB - Ultrasmall size Rh nanoparticles were synthesized and stabilized by the complex of cetyltrimethylammonium bromide and water-soluble ionic liquid molecules. The new catalytic system shows excellent catalytic activity in the oxidation of alcohols to aldehydes or ketones only in pure water through acceptorless dehydrogenation. It is atom economic, clean and green in the synthesis of aldehydes or ketones and H2 production at the same time.

KW - Catalyst

KW - Ionic liquid

KW - Nanoparticle

KW - Rhodium

KW - Water

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U2 - 10.1021/acssuschemeng.6b02994

DO - 10.1021/acssuschemeng.6b02994

M3 - Journal article

AN - SCOPUS:85014520043

SN - 2168-0485

VL - 5

SP - 2056

EP - 2060

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 3

ER -

Small Size Rh Nanoparticles in Micelle Nanostructure by Ionic Liquid/CTAB for Acceptorless Dehydrogenation of Alcohols Only in Pure Water

Abstract

Scopus Subject Areas

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UN SDGs

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