Simultaneous Primary and Secondary Coordination of a Neutral Guest within a Macrocyclic Complex of Rhodium(III)

George Ferguson; Karen E. Matthes; David Parker

doi:10.1002/anie.198711621

Simultaneous Primary and Secondary Coordination of a Neutral Guest within a Macrocyclic Complex of Rhodium(III)

George Ferguson^*
, Karen E. Matthes
, David Parker

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

18 Citations (Scopus)

Abstract

A remarkable coordination of a water molecule is the unique feature of the octahedral title compound 1. H₂O is bound primarily to Rh^III and secondarily by two stabilizing hydrogen bonds to the O atoms of the ligand. The two H atoms occupy three positions and form a third hydrogen bond to an F atom of PF 6⊖. (Figure Presented.)

Original language	English
Pages (from-to)	1162-1163
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	11
DOIs	https://doi.org/10.1002/anie.198711621
Publication status	Published - Nov 1987

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Cite this

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title = "Simultaneous Primary and Secondary Coordination of a Neutral Guest within a Macrocyclic Complex of Rhodium(III)",

abstract = "A remarkable coordination of a water molecule is the unique feature of the octahedral title compound 1. H2O is bound primarily to RhIII and secondarily by two stabilizing hydrogen bonds to the O atoms of the ligand. The two H atoms occupy three positions and form a third hydrogen bond to an F atom of PF 6⊖. (Figure Presented.)",

author = "George Ferguson and Matthes, \{Karen E.\} and David Parker",

note = "This work was supported by the Science and Engineering Research Council of the United Kingdom and NSERC (Canada). This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. ",

year = "1987",

month = nov,

doi = "10.1002/anie.198711621",

language = "English",

volume = "26",

pages = "1162--1163",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley \& Sons Ltd",

number = "11",

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T1 - Simultaneous Primary and Secondary Coordination of a Neutral Guest within a Macrocyclic Complex of Rhodium(III)

AU - Ferguson, George

AU - Matthes, Karen E.

AU - Parker, David

N1 - This work was supported by the Science and Engineering Research Council of the United Kingdom and NSERC (Canada). This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.

PY - 1987/11

Y1 - 1987/11

N2 - A remarkable coordination of a water molecule is the unique feature of the octahedral title compound 1. H2O is bound primarily to RhIII and secondarily by two stabilizing hydrogen bonds to the O atoms of the ligand. The two H atoms occupy three positions and form a third hydrogen bond to an F atom of PF 6⊖. (Figure Presented.)

AB - A remarkable coordination of a water molecule is the unique feature of the octahedral title compound 1. H2O is bound primarily to RhIII and secondarily by two stabilizing hydrogen bonds to the O atoms of the ligand. The two H atoms occupy three positions and form a third hydrogen bond to an F atom of PF 6⊖. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985559906

U2 - 10.1002/anie.198711621

DO - 10.1002/anie.198711621

M3 - Journal article

AN - SCOPUS:84985559906

SN - 0570-0833

VL - 26

SP - 1162

EP - 1163

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 11

ER -

Simultaneous Primary and Secondary Coordination of a Neutral Guest within a Macrocyclic Complex of Rhodium(III)

Abstract

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