Self-assembly of meso-tetrakis(4-N-ethylpyridiniurmyl) porphyrin and tetracarboxyl-phenyl calix[4]arene

Yingli Wei; Xiliang Guo; Shaomin Shuang; Chuan Dong; Xiaohua Sun; Manshing Wong

doi:10.1016/j.jphotobiol.2005.08.001

Self-assembly of meso-tetrakis(4-N-ethylpyridiniurmyl) porphyrin and tetracarboxyl-phenyl calix[4]arene

Yingli Wei, Xiliang Guo, Shaomin Shuang, Chuan Dong, Xiaohua Sun, Manshing Wong^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

10 Citations (Scopus)

Abstract

Novel dimeric capsules are generated from the noncovalent assembly of 5, 10, 15, 20-tetrakis(4-N-ethylpyridiniurmyl)prophyrin (TEPyP) and tetracarboxyl-phenyl calix[4]arene. The self-assembly system was investigated based on UV-Vis absorption and fluorescent spectra. The factors affecting the interaction process including pH and concentration were examined in detail. The association constants between TEPyP and calix[4]arene were determined by the nonlinear least squares fit. The results showed that the basic medium is favourable to the interaction and electrostatic interaction was determinate in the processes of self-assembly process. The related mechanism was discussed.

Original language	English
Pages (from-to)	190-194
Number of pages	5
Journal	Journal of Photochemistry and Photobiology B: Biology
Volume	81
Issue number	3
DOIs	https://doi.org/10.1016/j.jphotobiol.2005.08.001
Publication status	Published - 1 Dec 2005

User-Defined Keywords

Fluorescence
Meso-Tetrakis(4-N-ethylpyridiniurmyl)prophyrin
Self-assembly
Tetracarboxyl-phenyl calix[4]arene

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10.1016/j.jphotobiol.2005.08.001

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@article{a71209005bbb47f9b25200aa9ce8793b,

title = "Self-assembly of meso-tetrakis(4-N-ethylpyridiniurmyl) porphyrin and tetracarboxyl-phenyl calix[4]arene",

abstract = "Novel dimeric capsules are generated from the noncovalent assembly of 5, 10, 15, 20-tetrakis(4-N-ethylpyridiniurmyl)prophyrin (TEPyP) and tetracarboxyl-phenyl calix[4]arene. The self-assembly system was investigated based on UV-Vis absorption and fluorescent spectra. The factors affecting the interaction process including pH and concentration were examined in detail. The association constants between TEPyP and calix[4]arene were determined by the nonlinear least squares fit. The results showed that the basic medium is favourable to the interaction and electrostatic interaction was determinate in the processes of self-assembly process. The related mechanism was discussed.",

keywords = "Fluorescence, Meso-Tetrakis(4-N-ethylpyridiniurmyl)prophyrin, Self-assembly, Tetracarboxyl-phenyl calix[4]arene",

author = "Yingli Wei and Xiliang Guo and Shaomin Shuang and Chuan Dong and Xiaohua Sun and Manshing Wong",

note = "Funding Information: This work was supported by the National Natural Science Foundation of China (No. 20575038) and the Foundation of Shanxi Province (No. 20031019).",

year = "2005",

month = dec,

day = "1",

doi = "10.1016/j.jphotobiol.2005.08.001",

language = "English",

volume = "81",

pages = "190--194",

journal = "Journal of Photochemistry and Photobiology B: Biology",

issn = "1011-1344",

publisher = "Elsevier B.V.",

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T1 - Self-assembly of meso-tetrakis(4-N-ethylpyridiniurmyl) porphyrin and tetracarboxyl-phenyl calix[4]arene

AU - Wei, Yingli

AU - Guo, Xiliang

AU - Shuang, Shaomin

AU - Dong, Chuan

AU - Sun, Xiaohua

AU - Wong, Manshing

N1 - Funding Information: This work was supported by the National Natural Science Foundation of China (No. 20575038) and the Foundation of Shanxi Province (No. 20031019).

PY - 2005/12/1

Y1 - 2005/12/1

N2 - Novel dimeric capsules are generated from the noncovalent assembly of 5, 10, 15, 20-tetrakis(4-N-ethylpyridiniurmyl)prophyrin (TEPyP) and tetracarboxyl-phenyl calix[4]arene. The self-assembly system was investigated based on UV-Vis absorption and fluorescent spectra. The factors affecting the interaction process including pH and concentration were examined in detail. The association constants between TEPyP and calix[4]arene were determined by the nonlinear least squares fit. The results showed that the basic medium is favourable to the interaction and electrostatic interaction was determinate in the processes of self-assembly process. The related mechanism was discussed.

AB - Novel dimeric capsules are generated from the noncovalent assembly of 5, 10, 15, 20-tetrakis(4-N-ethylpyridiniurmyl)prophyrin (TEPyP) and tetracarboxyl-phenyl calix[4]arene. The self-assembly system was investigated based on UV-Vis absorption and fluorescent spectra. The factors affecting the interaction process including pH and concentration were examined in detail. The association constants between TEPyP and calix[4]arene were determined by the nonlinear least squares fit. The results showed that the basic medium is favourable to the interaction and electrostatic interaction was determinate in the processes of self-assembly process. The related mechanism was discussed.

KW - Fluorescence

KW - Meso-Tetrakis(4-N-ethylpyridiniurmyl)prophyrin

KW - Self-assembly

KW - Tetracarboxyl-phenyl calix[4]arene

UR - http://www.scopus.com/inward/record.url?scp=28444439225&partnerID=8YFLogxK

U2 - 10.1016/j.jphotobiol.2005.08.001

DO - 10.1016/j.jphotobiol.2005.08.001

M3 - Journal article

C2 - 16219471

AN - SCOPUS:28444439225

SN - 1011-1344

VL - 81

SP - 190

EP - 194

JO - Journal of Photochemistry and Photobiology B: Biology

JF - Journal of Photochemistry and Photobiology B: Biology

IS - 3

ER -

Self-assembly of meso-tetrakis(4-N-ethylpyridiniurmyl) porphyrin and tetracarboxyl-phenyl calix[4]arene

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