Scope and limitations of organometallic chiral derivatising agents for the 31p nmr determination of the enantiomeric purity of chiral η2 donors

D. Parker; R. J. Taylor

doi:10.1016/S0040-4020(01)81732-4

Scope and limitations of organometallic chiral derivatising agents for the ³¹p nmr determination of the enantiomeric purity of chiral η² donors

D. Parker^*
, R. J. Taylor

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

35 Citations (Scopus)

Abstract

The zerovalent platinum and palladium ethene complexes of 2,2-dimethyl-4,5-bis(diphenylphosphinomethyl)-l,3-dioxolan have been used as chiral derivatising agents for the ³¹P NMR assay of the enantiomeric purity of certain alkenes and allenes.

Original language	English
Pages (from-to)	2241-2248
Number of pages	8
Journal	Tetrahedron
Volume	44
Issue number	8
DOIs	https://doi.org/10.1016/S0040-4020(01)81732-4
Publication status	Published - Apr 1988

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title = "Scope and limitations of organometallic chiral derivatising agents for the 31p nmr determination of the enantiomeric purity of chiral η2 donors",

abstract = "The zerovalent platinum and palladium ethene complexes of 2,2-dimethyl-4,5-bis(diphenylphosphinomethyl)-l,3-dioxolan have been used as chiral derivatising agents for the 31P NMR assay of the enantiomeric purity of certain alkenes and allenes.",

author = "D. Parker and Taylor, \{R. J.\}",

note = "Copyright {\textcopyright} 1988 Published by Elsevier Ltd. ",

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AU - Parker, D.

AU - Taylor, R. J.

PY - 1988/4

Y1 - 1988/4

N2 - The zerovalent platinum and palladium ethene complexes of 2,2-dimethyl-4,5-bis(diphenylphosphinomethyl)-l,3-dioxolan have been used as chiral derivatising agents for the 31P NMR assay of the enantiomeric purity of certain alkenes and allenes.

AB - The zerovalent platinum and palladium ethene complexes of 2,2-dimethyl-4,5-bis(diphenylphosphinomethyl)-l,3-dioxolan have been used as chiral derivatising agents for the 31P NMR assay of the enantiomeric purity of certain alkenes and allenes.

UR - https://www.scopus.com/pages/publications/0000836175

U2 - 10.1016/S0040-4020(01)81732-4

DO - 10.1016/S0040-4020(01)81732-4

M3 - Journal article

AN - SCOPUS:0000836175

SN - 0040-4020

VL - 44

SP - 2241

EP - 2248

JO - Tetrahedron

JF - Tetrahedron

IS - 8

ER -

Scope and limitations of organometallic chiral derivatising agents for the ³¹p nmr determination of the enantiomeric purity of chiral η² donors

Abstract

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