Responsive fluorinated lanthanide probes for 19F magnetic resonance spectroscopy

P. Kanthi Senanayake; Alan M. Kenwright; David Parker; Susanna K. Van Der Hoorn

doi:10.1039/b705844f

Responsive fluorinated lanthanide probes for ¹⁹F magnetic resonance spectroscopy

P. Kanthi Senanayake
, Alan M. Kenwright
, David Parker^*
, Susanna K. Van Der Hoorn

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

55 Citations (Scopus)

Abstract

The introduction of CF₃ reporter groups close to the paramagnetic centre in macrocyclic lanthanide(iii) complexes allows faster acquisition of ¹⁹F magnetic resonance data, and amplifies chemical shift non-equivalence, as exemplified by the definition of ratiometric chemical shift probes for pH and, in principle, enzyme activity.

Original language	English
Pages (from-to)	2923-2925
Number of pages	3
Journal	Chemical Communications
Issue number	28
DOIs	https://doi.org/10.1039/b705844f
Publication status	Published - 21 Jun 2007

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10.1039/b705844f

Cite this

@article{b284aba776dc413b82c3483b8b5a22f3,

title = "Responsive fluorinated lanthanide probes for 19F magnetic resonance spectroscopy",

abstract = "The introduction of CF3 reporter groups close to the paramagnetic centre in macrocyclic lanthanide(iii) complexes allows faster acquisition of 19F magnetic resonance data, and amplifies chemical shift non-equivalence, as exemplified by the definition of ratiometric chemical shift probes for pH and, in principle, enzyme activity.",

author = "Senanayake, \{P. Kanthi\} and Kenwright, \{Alan M.\} and David Parker and \{Van Der Hoorn\}, \{Susanna K.\}",

note = "We thank EPSRC (LSI Platform grant) and the Royal Society for support. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2007",

year = "2007",

month = jun,

day = "21",

doi = "10.1039/b705844f",

language = "English",

pages = "2923--2925",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "28",

}

TY - JOUR

T1 - Responsive fluorinated lanthanide probes for 19F magnetic resonance spectroscopy

AU - Senanayake, P. Kanthi

AU - Kenwright, Alan M.

AU - Parker, David

AU - Van Der Hoorn, Susanna K.

PY - 2007/6/21

Y1 - 2007/6/21

N2 - The introduction of CF3 reporter groups close to the paramagnetic centre in macrocyclic lanthanide(iii) complexes allows faster acquisition of 19F magnetic resonance data, and amplifies chemical shift non-equivalence, as exemplified by the definition of ratiometric chemical shift probes for pH and, in principle, enzyme activity.

AB - The introduction of CF3 reporter groups close to the paramagnetic centre in macrocyclic lanthanide(iii) complexes allows faster acquisition of 19F magnetic resonance data, and amplifies chemical shift non-equivalence, as exemplified by the definition of ratiometric chemical shift probes for pH and, in principle, enzyme activity.

UR - https://www.scopus.com/pages/publications/34447318335

UR - https://pubs.rsc.org/en/content/articlelanding/2007/cc/b705844f

U2 - 10.1039/b705844f

DO - 10.1039/b705844f

M3 - Journal article

AN - SCOPUS:34447318335

SN - 1359-7345

SP - 2923

EP - 2925

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Responsive fluorinated lanthanide probes for ¹⁹F magnetic resonance spectroscopy

Abstract

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