Regulating the vertical phase distribution by fullerene-derivative in high performance ternary organic solar cells

The vertical phase distribution of components in bulk heterojunction is diversified in organic solar cells (OSCs). The electron donors (acceptors) can be accumulated (depleted) at the interface of active layer and charge extraction layer. The variation of vertical phase distribution significantly influences device performance because of its impact on the charge transport and charge recombination. In order to achieve favorable vertical phase distribution in OSCs based on poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b′]dithiophene))-co-(1,3-di(5-thiophene-2-yl)–5,7-bis(2-ethylhexyl) benzo[1,2-c:4,5-c′]dithiophene-4,8-dione)] (PBDB-T):3,9-bis(2-methylene-(3-(1,1-dicyanomethylene)-indanone))−5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2′,3′-d′]-s-indaceno[1,2-b:5,6-b′]-dithiophene (ITIC), phenyl-C71-butyric-acid-methyl ester (PC₇₁BM) was incorporated into the binary system to fabricate ternary OSCs. In the ternary blend, PC₇₁BM can effectively regulate the phase distribution of PBDB-T and ITIC in vertical direction, which provides favorable vertical phase distribution for charge transport. Moreover, the addition of PC₇₁BM can also effectively increase the π-π stacking coherence length of both donor and acceptor, which facilitates charge transport and reduces the bimolecular recombination. The addition of an appropriate quantity of PC₇₁BM can obviously improve both fill factor and short-circuit current density of the OSC based on PBDB-T:ITIC while open-circuit voltage reduces only about 0.01 V, which indicates a rational low energy loss. Consequently, the ternary OSC exhibits a best PCE of 11.0% compared to the 9.6% PCE of the binary counterpart.