Reactivity of Group 10 halides toward (Ph2PN=)C(Ph)[N(SiMe3)2], (NC5H4){(Ph2PN=)C[N(SiMe3) 2]}-4 and C6H4{C(=NPPh2)[N(SiMe3) 2]}2-1,4

Rick W K WONG; Chaode Sun; Wing Tak Wong

doi:10.1039/a703005c

Reactivity of Group 10 halides toward (Ph₂PN=)C(Ph)[N(SiMe₃)₂], (NC₅H₄){(Ph₂PN=)C[N(SiMe₃) ₂]}-4 and C₆H₄{C(=NPPh₂)[N(SiMe₃) ₂]}₂-1,4

Rick W K WONG^*, Chaode Sun, Wing Tak Wong

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

11 Citations (Scopus)

Abstract

Interaction of [NiBr₂(dme)] (dme = 1,2-dimethoxyethane) with 1 equivalent of (Ph₂PN=)C(Ph)[N(SiMe₃)₂] L¹ in tetrahydrofuran gave cis-[NiBr₂{(Ph₂PNH)C(Ph)(=NH)}] 1, metathesis of this compound with excess NH₄BF₄ in methanol gave cis-[Ni{(Ph₂PNH)C(Ph)(=NH)}₂][BF₄]₂ 2. Reaction of [NiBr₂(dme)] with 1 equivalent of (NC₅H₄){Ph₂PN=)C[N(SiMe₃) ₂]}-4 L³ followed by metathesis with excess NH₄BF₄ in methanol gave cis-[Ni{(NC₅H₄)[(Ph₂PNH)C(=NH)]-4} ₂[BF₄]₂ 3. Reaction of [PdCl₂(PhCN)₂] with 1 equivalent of L¹ in acetonitrile gave cis-[PdCl₂{(Ph₂PNH)C(Ph)(=NH)}] 4, and with 0.5 equivalent of C₆H₄{C(=NPPh₂)[N(SiMe₃) ₂]}₂-1,4 L² in tetrahydrofuran gave cis-[(PdCl₂)₂{C₆H₄[C(=NPPh ₂){N(SiMe₃)₂}]₂-1,4}] 5 and cis-[(PdCl₂)₂{C₆H₄[C(NHPPh ₂)-(=NH)]₂-1,4}] 6. Interaction of [PdCl₂(PhCN)₂] with L³ in 1:1 and 3:2 molar ratios gave cis-[PdCl₂{(NC₅H₄)-[(Ph ₂PNH)C(=NH)]-4}] 7 and trans-[PdCl₂{cis-PdCl₂[(NC₅H ₄){(Ph₂PNH)C(=NH)}-4]}₂] 8, respectively. Reaction of [MCl₂(PhCN)₂] (M = Pd or Pt) with 2 equivalents of L³ followed by metathesis with excess NH₄BF₄ in methanol gave cis-[M{(NC₅H₄)[(Ph₂PNH)C(=NH)]-4}{(NC ₅H₄)[(Ph₂PNH)C(=N)]-4}][BF₄] (Pd 9 or Pt 10). Crystal structures of compounds 1, 4, 7, 8, 9 and 10 have been determined.

Original language	English
Pages (from-to)	3387-3395
Number of pages	9
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	18
DOIs	https://doi.org/10.1039/a703005c
Publication status	Published - 21 Sept 1997

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@article{c13ca060ecf64b8397920f29fa0aec61,

title = "Reactivity of Group 10 halides toward (Ph2PN=)C(Ph)[N(SiMe3)2], (NC5H4){(Ph2PN=)C[N(SiMe3) 2]}-4 and C6H4{C(=NPPh2)[N(SiMe3) 2]}2-1,4",

abstract = "Interaction of [NiBr2(dme)] (dme = 1,2-dimethoxyethane) with 1 equivalent of (Ph2PN=)C(Ph)[N(SiMe3)2] L1 in tetrahydrofuran gave cis-[NiBr2{(Ph2PNH)C(Ph)(=NH)}] 1, metathesis of this compound with excess NH4BF4 in methanol gave cis-[Ni{(Ph2PNH)C(Ph)(=NH)}2][BF4]2 2. Reaction of [NiBr2(dme)] with 1 equivalent of (NC5H4){Ph2PN=)C[N(SiMe3) 2]}-4 L3 followed by metathesis with excess NH4BF4 in methanol gave cis-[Ni{(NC5H4)[(Ph2PNH)C(=NH)]-4} 2[BF4]2 3. Reaction of [PdCl2(PhCN)2] with 1 equivalent of L1 in acetonitrile gave cis-[PdCl2{(Ph2PNH)C(Ph)(=NH)}] 4, and with 0.5 equivalent of C6H4{C(=NPPh2)[N(SiMe3) 2]}2-1,4 L2 in tetrahydrofuran gave cis-[(PdCl2)2{C6H4[C(=NPPh 2){N(SiMe3)2}]2-1,4}] 5 and cis-[(PdCl2)2{C6H4[C(NHPPh 2)-(=NH)]2-1,4}] 6. Interaction of [PdCl2(PhCN)2] with L3 in 1:1 and 3:2 molar ratios gave cis-[PdCl2{(NC5H4)-[(Ph 2PNH)C(=NH)]-4}] 7 and trans-[PdCl2{cis-PdCl2[(NC5H 4){(Ph2PNH)C(=NH)}-4]}2] 8, respectively. Reaction of [MCl2(PhCN)2] (M = Pd or Pt) with 2 equivalents of L3 followed by metathesis with excess NH4BF4 in methanol gave cis-[M{(NC5H4)[(Ph2PNH)C(=NH)]-4}{(NC 5H4)[(Ph2PNH)C(=N)]-4}][BF4] (Pd 9 or Pt 10). Crystal structures of compounds 1, 4, 7, 8, 9 and 10 have been determined.",

author = "WONG, {Rick W K} and Chaode Sun and Wong, {Wing Tak}",

year = "1997",

month = sep,

day = "21",

doi = "10.1039/a703005c",

language = "English",

pages = "3387--3395",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "18",

}

TY - JOUR

T1 - Reactivity of Group 10 halides toward (Ph2PN=)C(Ph)[N(SiMe3)2], (NC5H4){(Ph2PN=)C[N(SiMe3) 2]}-4 and C6H4{C(=NPPh2)[N(SiMe3) 2]}2-1,4

AU - WONG, Rick W K

AU - Sun, Chaode

AU - Wong, Wing Tak

PY - 1997/9/21

Y1 - 1997/9/21

N2 - Interaction of [NiBr2(dme)] (dme = 1,2-dimethoxyethane) with 1 equivalent of (Ph2PN=)C(Ph)[N(SiMe3)2] L1 in tetrahydrofuran gave cis-[NiBr2{(Ph2PNH)C(Ph)(=NH)}] 1, metathesis of this compound with excess NH4BF4 in methanol gave cis-[Ni{(Ph2PNH)C(Ph)(=NH)}2][BF4]2 2. Reaction of [NiBr2(dme)] with 1 equivalent of (NC5H4){Ph2PN=)C[N(SiMe3) 2]}-4 L3 followed by metathesis with excess NH4BF4 in methanol gave cis-[Ni{(NC5H4)[(Ph2PNH)C(=NH)]-4} 2[BF4]2 3. Reaction of [PdCl2(PhCN)2] with 1 equivalent of L1 in acetonitrile gave cis-[PdCl2{(Ph2PNH)C(Ph)(=NH)}] 4, and with 0.5 equivalent of C6H4{C(=NPPh2)[N(SiMe3) 2]}2-1,4 L2 in tetrahydrofuran gave cis-[(PdCl2)2{C6H4[C(=NPPh 2){N(SiMe3)2}]2-1,4}] 5 and cis-[(PdCl2)2{C6H4[C(NHPPh 2)-(=NH)]2-1,4}] 6. Interaction of [PdCl2(PhCN)2] with L3 in 1:1 and 3:2 molar ratios gave cis-[PdCl2{(NC5H4)-[(Ph 2PNH)C(=NH)]-4}] 7 and trans-[PdCl2{cis-PdCl2[(NC5H 4){(Ph2PNH)C(=NH)}-4]}2] 8, respectively. Reaction of [MCl2(PhCN)2] (M = Pd or Pt) with 2 equivalents of L3 followed by metathesis with excess NH4BF4 in methanol gave cis-[M{(NC5H4)[(Ph2PNH)C(=NH)]-4}{(NC 5H4)[(Ph2PNH)C(=N)]-4}][BF4] (Pd 9 or Pt 10). Crystal structures of compounds 1, 4, 7, 8, 9 and 10 have been determined.

AB - Interaction of [NiBr2(dme)] (dme = 1,2-dimethoxyethane) with 1 equivalent of (Ph2PN=)C(Ph)[N(SiMe3)2] L1 in tetrahydrofuran gave cis-[NiBr2{(Ph2PNH)C(Ph)(=NH)}] 1, metathesis of this compound with excess NH4BF4 in methanol gave cis-[Ni{(Ph2PNH)C(Ph)(=NH)}2][BF4]2 2. Reaction of [NiBr2(dme)] with 1 equivalent of (NC5H4){Ph2PN=)C[N(SiMe3) 2]}-4 L3 followed by metathesis with excess NH4BF4 in methanol gave cis-[Ni{(NC5H4)[(Ph2PNH)C(=NH)]-4} 2[BF4]2 3. Reaction of [PdCl2(PhCN)2] with 1 equivalent of L1 in acetonitrile gave cis-[PdCl2{(Ph2PNH)C(Ph)(=NH)}] 4, and with 0.5 equivalent of C6H4{C(=NPPh2)[N(SiMe3) 2]}2-1,4 L2 in tetrahydrofuran gave cis-[(PdCl2)2{C6H4[C(=NPPh 2){N(SiMe3)2}]2-1,4}] 5 and cis-[(PdCl2)2{C6H4[C(NHPPh 2)-(=NH)]2-1,4}] 6. Interaction of [PdCl2(PhCN)2] with L3 in 1:1 and 3:2 molar ratios gave cis-[PdCl2{(NC5H4)-[(Ph 2PNH)C(=NH)]-4}] 7 and trans-[PdCl2{cis-PdCl2[(NC5H 4){(Ph2PNH)C(=NH)}-4]}2] 8, respectively. Reaction of [MCl2(PhCN)2] (M = Pd or Pt) with 2 equivalents of L3 followed by metathesis with excess NH4BF4 in methanol gave cis-[M{(NC5H4)[(Ph2PNH)C(=NH)]-4}{(NC 5H4)[(Ph2PNH)C(=N)]-4}][BF4] (Pd 9 or Pt 10). Crystal structures of compounds 1, 4, 7, 8, 9 and 10 have been determined.

UR - http://www.scopus.com/inward/record.url?scp=33748635213&partnerID=8YFLogxK

U2 - 10.1039/a703005c

DO - 10.1039/a703005c

M3 - Journal article

AN - SCOPUS:33748635213

SN - 0300-9246

SP - 3387

EP - 3395

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 18

ER -

Reactivity of Group 10 halides toward (Ph₂PN=)C(Ph)[N(SiMe₃)₂], (NC₅H₄){(Ph₂PN=)C[N(SiMe₃) ₂]}-4 and C₆H₄{C(=NPPh₂)[N(SiMe₃) ₂]}₂-1,4

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