Reactivity of chiral diiminodiphosphine ligands towards pdCl2(PhCN)2: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

Rick W K WONG; Li Lu Zhang; Yang Chen; Wai Yeung WONG; Wing Tak Wong; Feng Xuc; Thomas C.W. Mak

doi:10.1039/b001245i

Reactivity of chiral diiminodiphosphine ligands towards pdCl₂(PhCN)₂: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

Rick W K WONG^*, Li Lu Zhang, Yang Chen, Wai Yeung WONG, Wing Tak Wong, Feng Xuc, Thomas C.W. Mak

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

11 Citations (Scopus)

Abstract

The interaction of PdCl₂(PhCN)₂ with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[₂-(Ph₂P)C₆H₄CH=N]}₂ 1 and the dinuclear complex {ci5-PdCl₂[2-(Ph₂P)C₆H₄CH= NCH(Ph)CH(C₆H₄PPh₂-2)=NC₆H ₄(PPh₂)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.

Original language	English
Pages (from-to)	1397-1398
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/b001245i
Publication status	Published - 10 Apr 2000

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@article{08fe062c123340d48cf2e676d5d5575e,

title = "Reactivity of chiral diiminodiphosphine ligands towards pdCl2(PhCN)2: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes",

abstract = "The interaction of PdCl2(PhCN)2 with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}2 1 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H 4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.",

author = "WONG, {Rick W K} and Zhang, {Li Lu} and Yang Chen and WONG, {Wai Yeung} and Wong, {Wing Tak} and Feng Xuc and Mak, {Thomas C.W.}",

year = "2000",

month = apr,

day = "10",

doi = "10.1039/b001245i",

language = "English",

pages = "1397--1398",

journal = " Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "9",

}

Reactivity of chiral diiminodiphosphine ligands towards pdCl₂(PhCN)₂: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes. / WONG, Rick W K; Zhang, Li Lu; Chen, Yang et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 9, 10.04.2000, p. 1397-1398.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Reactivity of chiral diiminodiphosphine ligands towards pdCl2(PhCN)2

T2 - Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

AU - WONG, Rick W K

AU - Zhang, Li Lu

AU - Chen, Yang

AU - WONG, Wai Yeung

AU - Wong, Wing Tak

AU - Xuc, Feng

AU - Mak, Thomas C.W.

PY - 2000/4/10

Y1 - 2000/4/10

N2 - The interaction of PdCl2(PhCN)2 with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}2 1 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H 4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.

AB - The interaction of PdCl2(PhCN)2 with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}2 1 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H 4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.

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U2 - 10.1039/b001245i

DO - 10.1039/b001245i

M3 - Journal article

AN - SCOPUS:0002576733

SN - 0300-9246

SP - 1397

EP - 1398

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 9

ER -

Reactivity of chiral diiminodiphosphine ligands towards pdCl₂(PhCN)₂: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

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