Reactivity of chiral diiminodiphosphine ligands towards pdCl2(PhCN)2: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

Rick W K WONG*, Li Lu Zhang, Yang Chen, Wai Yeung WONG, Wing Tak Wong, Feng Xuc, Thomas C.W. Mak

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The interaction of PdCl2(PhCN)2 with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}2 1 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H 4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.

Original languageEnglish
Pages (from-to)1397-1398
Number of pages2
JournalJournal of the Chemical Society. Dalton Transactions
Issue number9
DOIs
Publication statusPublished - 2000

Scopus Subject Areas

  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Reactivity of chiral diiminodiphosphine ligands towards pdCl<sub>2</sub>(PhCN)<sub>2</sub>: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes'. Together they form a unique fingerprint.

Cite this