Quantum effect and Mo-N surface bonding states of a-MoC 1-x modified carbon nitride for boosting photocatalytic performance

Zhi Zhu, Reeti Kumar, Liwen Luo, Sunita Varjani, Pengwei Huo, Jonathan Woon Chung Wong*, Jun Zhao*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Photocatalytic degradation of pharmaceuticals in the aquatic environment is considered a promising strategy to address water pollution. In this study, a novel photocatalyst was constructed by decorating g-C 3N 4 (CN) with a-MoC 1-x quantum dots (a-MoC 1-x-QDs) through a facile calcination method. The catalyst showed enhanced tetracycline (TC) degradation performance under visible light. The unique Mo-N surface bonding states and quantum effect leading to superior TC degradation activity (89.1%) compared to pure CN (21.8%) were reported and revealed. More importantly, the mechanism for the significant enhancement of photocatalytic activity of the catalyst was investigated by DFT (density functional theory) calculations and photo-electrochemistry measurements. The results confirmed that the effect of a-MoC 1-x-QDs on CN improved the light absorption capacity obviously, and the Mo-N surface bonding states accelerated the charge migration from CN to a-MoC 1-x-QDs. Moreover, the TC degradation pathway, intermediates and photogenerated carrier transfer behaviors were also discussed in depth. This research provides a new strategy for the construction of noble-metal-free co-catalyst/semiconductor composite materials in the photocatalytic degradation of antibiotics.

Original languageEnglish
Pages (from-to)6384-6397
Number of pages14
JournalCatalysis Science and Technology
Volume12
Issue number21
Early online date29 Aug 2022
DOIs
Publication statusPublished - 7 Nov 2022

Scopus Subject Areas

  • Catalysis

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