Proton-bridged dinuclear (salen)Ru carbene complexes: Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh2)]2 ·H}+

Chun Yuen Wong; Wai Lun MAN; Chao Wang; Hoi Lun Kwong; Wai Yeung WONG; Tai Chu Lau

doi:10.1021/om701166y

Proton-bridged dinuclear (salen)Ru carbene complexes: Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh₂)]₂ ·H}⁺

Chun Yuen Wong^*, Wai Lun MAN, Chao Wang, Hoi Lun Kwong, Wai Yeung WONG, Tai Chu Lau

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

22 Citations (Scopus)

Abstract

Hydrogen-bridged dinuclear ruthenium carbene complexes supported by salen have been prepared and found to be active catalysts for the cyclopropanation of alkenes; electrochemical and theoretical studies suggest the existence of electronic communication between the Ru centers.

Original language	English
Pages (from-to)	324-326
Number of pages	3
Journal	Organometallics
Volume	27
Issue number	3
DOIs	https://doi.org/10.1021/om701166y
Publication status	Published - 11 Feb 2008

Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om701166y

Cite this

@article{b3335c2a3d094ea8a8f9918473f63bc0,

title = "Proton-bridged dinuclear (salen)Ru carbene complexes: Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh2)]2 ·H}+",

abstract = "Hydrogen-bridged dinuclear ruthenium carbene complexes supported by salen have been prepared and found to be active catalysts for the cyclopropanation of alkenes; electrochemical and theoretical studies suggest the existence of electronic communication between the Ru centers.",

author = "Wong, {Chun Yuen} and MAN, {Wai Lun} and Chao Wang and Kwong, {Hoi Lun} and WONG, {Wai Yeung} and Lau, {Tai Chu}",

note = "The work described in this paper was supported by grants from City University of Hong Kong (Nos. 7002089 (C.-Y.W.) and 7001799 (T.-C.L.)) and the Research Grants Council of Hong Kong (CityU No. 101404 (T.-C.L.)). ",

year = "2008",

month = feb,

day = "11",

doi = "10.1021/om701166y",

language = "English",

volume = "27",

pages = "324--326",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Proton-bridged dinuclear (salen)Ru carbene complexes

T2 - Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh2)]2 ·H}+

AU - Wong, Chun Yuen

AU - MAN, Wai Lun

AU - Wang, Chao

AU - Kwong, Hoi Lun

AU - WONG, Wai Yeung

AU - Lau, Tai Chu

N1 - The work described in this paper was supported by grants from City University of Hong Kong (Nos. 7002089 (C.-Y.W.) and 7001799 (T.-C.L.)) and the Research Grants Council of Hong Kong (CityU No. 101404 (T.-C.L.)).

PY - 2008/2/11

Y1 - 2008/2/11

N2 - Hydrogen-bridged dinuclear ruthenium carbene complexes supported by salen have been prepared and found to be active catalysts for the cyclopropanation of alkenes; electrochemical and theoretical studies suggest the existence of electronic communication between the Ru centers.

AB - Hydrogen-bridged dinuclear ruthenium carbene complexes supported by salen have been prepared and found to be active catalysts for the cyclopropanation of alkenes; electrochemical and theoretical studies suggest the existence of electronic communication between the Ru centers.

UR - http://www.scopus.com/inward/record.url?scp=39649115627&partnerID=8YFLogxK

U2 - 10.1021/om701166y

DO - 10.1021/om701166y

M3 - Journal article

AN - SCOPUS:39649115627

SN - 0276-7333

VL - 27

SP - 324

EP - 326

JO - Organometallics

JF - Organometallics

IS - 3

ER -

Proton-bridged dinuclear (salen)Ru carbene complexes: Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh₂)]₂ ·H}⁺

Abstract

Scopus Subject Areas

Access to Document

Other files and links

Fingerprint

Cite this