Preparation of triethylenetetramine-modified zirconosilicate molecular sieve for carbon dioxide adsorption

Fan Ming Yang, Lang Chen, Chak Tong AU, Shuang Feng Yin*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Mesoporous molecular sieve Zr-MCM-41 was modified with triethylenetetramine (TETA) and tested for carbon dioxide (CO2) adsorption for the first time. The adsorbent was characterized by powder X-ray diffraction, N2 adsorption-desorption, energy dispersive spectrometer, Fourier transform-infrared spectroscopy, thermogravimetric analysis, and temperature-programmed desorption of CO2 and NH3. A maximum CO2 adsorption capacity of 3.36 mmol g-1 at 50°C in a stream of 5% CO2 concentration was obtained, which is 2.7 times that of TETA-functionalized MCM-41. The TETA-modified Zr-MCM-41 is 30°C higher than the TETA-modified MCM-41 in terms of thermal stability. We find that the former adsorbent is superior in reusability. It is envisaged that the adsorbent is applicable in CO2 capture.

Original languageEnglish
Pages (from-to)1814-1821
Number of pages8
JournalEnvironmental Progress and Sustainable Energy
Volume34
Issue number6
DOIs
Publication statusPublished - 1 Nov 2015

Scopus Subject Areas

  • Environmental Engineering
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment
  • Water Science and Technology
  • Waste Management and Disposal
  • Environmental Science(all)

User-Defined Keywords

  • adsorption
  • carbon dioxide
  • MCM-41
  • triethylenetetramine
  • Zr-MCM-41

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