Preparation and characterization of iron(+2) and ruthenium (+2) diiminodiphosphine complexes. X-ray crystal structures of [(η5-C5H5)Fe(immpho)] [BF4]·0.5CH2Cl2 and {[(η5-C5Me5)Ru(CH3CN)] 2[immpho]} (ZnCl4)·2CH3CN·2H2O

Rick W K WONG; Yang Chen; Wing Tak Wong

doi:10.1016/0277-5387(96)00296-3

Preparation and characterization of iron(+2) and ruthenium (+2) diiminodiphosphine complexes. X-ray crystal structures of [(η⁵-C₅H₅)Fe(immpho)] [BF₄]·0.5CH₂Cl₂ and {[(η⁵-C₅Me₅)Ru(CH₃CN)] ₂[immpho]} (ZnCl₄)·2CH₃CN·2H₂O

Rick W K WONG^*, Yang Chen, Wing Tak Wong

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

11 Citations (Scopus)

Abstract

The interaction of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (immpho) with one and two equivalents of [(η⁵-C₅Me₅)Ru(CH₃CN) ₃]⁺ (generated in situ from the reaction of [(η⁵-C₅Me₅)RuCl₂]_n with excess Zn granular in CH₃CN) in CH₃CN at room temperature gave [(η⁵-C₅Me₅)Ru(immpho)] ₂[ZnCl₄] (I) and {[(η⁵-C₅Me₅)Ru(CH₃CN)] ₂[immpho]}{ZnCl₄} (II) in 80% and 71% yield, respectively. Upon UV irradiation, immpho reacted with equal molar of [(η⁵C₅H₅)Fe(η ⁶-mesitylene)][BF₄] in CH₃CN at room temperature to give [(η⁵-C₅H₅)Fe(immpho)][BF₄] (III) in 41% yield. Compounds I-III have been fully characterized by analytical and spectroscopic methods. The structures of II and III have been established by X-ray diffraction.

Original language	English
Pages (from-to)	433-439
Number of pages	7
Journal	Polyhedron
Volume	16
Issue number	3
DOIs	https://doi.org/10.1016/0277-5387(96)00296-3
Publication status	Published - 1997

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Cyclopentadienyl
Diiminodiphosphine
Iron(+2)
Pentamethylcyclopentadienyl
Ruthenium(+2)
Ruthenium(+2) dimer

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@article{f6df03c0e63a4f6696d69a0501052aef,

title = "Preparation and characterization of iron(+2) and ruthenium (+2) diiminodiphosphine complexes. X-ray crystal structures of [(η5-C5H5)Fe(immpho)] [BF4]·0.5CH2Cl2 and {[(η5-C5Me5)Ru(CH3CN)] 2[immpho]} (ZnCl4)·2CH3CN·2H2O",

abstract = "The interaction of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (immpho) with one and two equivalents of [(η5-C5Me5)Ru(CH3CN) 3]+ (generated in situ from the reaction of [(η5-C5Me5)RuCl2]n with excess Zn granular in CH3CN) in CH3CN at room temperature gave [(η5-C5Me5)Ru(immpho)] 2[ZnCl4] (I) and {[(η5-C5Me5)Ru(CH3CN)] 2[immpho]}{ZnCl4} (II) in 80% and 71% yield, respectively. Upon UV irradiation, immpho reacted with equal molar of [(η5C5H5)Fe(η 6-mesitylene)][BF4] in CH3CN at room temperature to give [(η5-C5H5)Fe(immpho)][BF4] (III) in 41% yield. Compounds I-III have been fully characterized by analytical and spectroscopic methods. The structures of II and III have been established by X-ray diffraction.",

keywords = "Cyclopentadienyl, Diiminodiphosphine, Iron(+2), Pentamethylcyclopentadienyl, Ruthenium(+2), Ruthenium(+2) dimer",

author = "WONG, {Rick W K} and Yang Chen and Wong, {Wing Tak}",

year = "1997",

doi = "10.1016/0277-5387(96)00296-3",

language = "English",

volume = "16",

pages = "433--439",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "3",

}

Preparation and characterization of iron(+2) and ruthenium (+2) diiminodiphosphine complexes. X-ray crystal structures of [(η⁵-C₅H₅)Fe(immpho)] [BF₄]·0.5CH₂Cl₂ and {[(η⁵-C₅Me₅)Ru(CH₃CN)] ₂[immpho]} (ZnCl₄)·2CH₃CN·2H₂O. / WONG, Rick W K; Chen, Yang; Wong, Wing Tak.
In: Polyhedron, Vol. 16, No. 3, 1997, p. 433-439.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Preparation and characterization of iron(+2) and ruthenium (+2) diiminodiphosphine complexes. X-ray crystal structures of [(η5-C5H5)Fe(immpho)] [BF4]·0.5CH2Cl2 and {[(η5-C5Me5)Ru(CH3CN)] 2[immpho]} (ZnCl4)·2CH3CN·2H2O

AU - WONG, Rick W K

AU - Chen, Yang

AU - Wong, Wing Tak

PY - 1997

Y1 - 1997

N2 - The interaction of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (immpho) with one and two equivalents of [(η5-C5Me5)Ru(CH3CN) 3]+ (generated in situ from the reaction of [(η5-C5Me5)RuCl2]n with excess Zn granular in CH3CN) in CH3CN at room temperature gave [(η5-C5Me5)Ru(immpho)] 2[ZnCl4] (I) and {[(η5-C5Me5)Ru(CH3CN)] 2[immpho]}{ZnCl4} (II) in 80% and 71% yield, respectively. Upon UV irradiation, immpho reacted with equal molar of [(η5C5H5)Fe(η 6-mesitylene)][BF4] in CH3CN at room temperature to give [(η5-C5H5)Fe(immpho)][BF4] (III) in 41% yield. Compounds I-III have been fully characterized by analytical and spectroscopic methods. The structures of II and III have been established by X-ray diffraction.

AB - The interaction of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (immpho) with one and two equivalents of [(η5-C5Me5)Ru(CH3CN) 3]+ (generated in situ from the reaction of [(η5-C5Me5)RuCl2]n with excess Zn granular in CH3CN) in CH3CN at room temperature gave [(η5-C5Me5)Ru(immpho)] 2[ZnCl4] (I) and {[(η5-C5Me5)Ru(CH3CN)] 2[immpho]}{ZnCl4} (II) in 80% and 71% yield, respectively. Upon UV irradiation, immpho reacted with equal molar of [(η5C5H5)Fe(η 6-mesitylene)][BF4] in CH3CN at room temperature to give [(η5-C5H5)Fe(immpho)][BF4] (III) in 41% yield. Compounds I-III have been fully characterized by analytical and spectroscopic methods. The structures of II and III have been established by X-ray diffraction.

KW - Cyclopentadienyl

KW - Diiminodiphosphine

KW - Iron(+2)

KW - Pentamethylcyclopentadienyl

KW - Ruthenium(+2)

KW - Ruthenium(+2) dimer

UR - http://www.scopus.com/inward/record.url?scp=0000207255&partnerID=8YFLogxK

U2 - 10.1016/0277-5387(96)00296-3

DO - 10.1016/0277-5387(96)00296-3

M3 - Journal article

AN - SCOPUS:0000207255

SN - 0277-5387

VL - 16

SP - 433

EP - 439

JO - Polyhedron

JF - Polyhedron

IS - 3

ER -