Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions

Chun Leung Kwok; Shun Cheung Cheng; Pui Yu Ho; Shek Man Yiu; Wai Lun Man; Vonika Ka Man Au; Po Keung Tsang; Chi Fai Leung; Chi Chiu Ko; Marc Robert

doi:10.1039/D0CC02604B

Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions

Chun Leung Kwok
, Shun Cheung Cheng
, Pui Yu Ho
, Shek Man Yiu
, Wai Lun Man
, Vonika Ka Man Au
, Po Keung Tsang
, Chi Fai Leung^*
, Chi Chiu Ko^*
, Marc Robert^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

12 Citations (Scopus)

Abstract

The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively.

Original language	English
Pages (from-to)	7491-7494
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	54
DOIs	https://doi.org/10.1039/D0CC02604B
Publication status	Published - 11 Jul 2020

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title = "Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions",

abstract = "The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively.",

author = "Kwok, \{Chun Leung\} and Cheng, \{Shun Cheung\} and Ho, \{Pui Yu\} and Yiu, \{Shek Man\} and Man, \{Wai Lun\} and Au, \{Vonika Ka Man\} and Tsang, \{Po Keung\} and Leung, \{Chi Fai\} and Ko, \{Chi Chiu\} and Marc Robert",

note = "Funding Information: The project was financially supported by the HK Research Grants Council (project number 18300715 and 18301418). Financial support (SGF-23) from EdUHK is also acknowledged.",

year = "2020",

month = jul,

day = "11",

doi = "10.1039/D0CC02604B",

language = "English",

volume = "56",

pages = "7491--7494",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions

AU - Kwok, Chun Leung

AU - Cheng, Shun Cheung

AU - Ho, Pui Yu

AU - Yiu, Shek Man

AU - Man, Wai Lun

AU - Au, Vonika Ka Man

AU - Tsang, Po Keung

AU - Leung, Chi Fai

AU - Ko, Chi Chiu

AU - Robert, Marc

N1 - Funding Information: The project was financially supported by the HK Research Grants Council (project number 18300715 and 18301418). Financial support (SGF-23) from EdUHK is also acknowledged.

PY - 2020/7/11

Y1 - 2020/7/11

N2 - The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively.

AB - The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively.

UR - https://www.scopus.com/pages/publications/85087751478

U2 - 10.1039/D0CC02604B

DO - 10.1039/D0CC02604B

M3 - Journal article

C2 - 32497158

AN - SCOPUS:85087751478

SN - 1359-7345

VL - 56

SP - 7491

EP - 7494

JO - Chemical Communications

JF - Chemical Communications

IS - 54

ER -

Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions

Abstract

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