Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions

Chun Leung Kwok; Shun Cheung Cheng; Pui Yu Ho; Shek Man Yiu; Wai Lun MAN; Vonika Ka Man Au; Po Keung Tsang; Chi Fai Leung; Chi Chiu Ko; Marc Robert

doi:10.1039/D0CC02604B

Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions

Chun Leung Kwok, Shun Cheung Cheng, Pui Yu Ho, Shek Man Yiu, Wai Lun MAN, Vonika Ka Man Au, Po Keung Tsang, Chi Fai Leung^*, Chi Chiu Ko, Marc Robert

^*Corresponding author for this work

Department of Chemistry

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Abstract

The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively. This journal is

Original language	English
Pages (from-to)	7491-7494
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	54
DOIs	https://doi.org/10.1039/D0CC02604B
Publication status	Published - 11 Jul 2020

Scopus Subject Areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/D0CC02604B

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Kwok, Chun Leung ; Cheng, Shun Cheung ; Ho, Pui Yu ; Yiu, Shek Man ; MAN, Wai Lun ; Au, Vonika Ka Man ; Tsang, Po Keung ; Leung, Chi Fai ; Ko, Chi Chiu ; Robert, Marc. / Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions. In: Chemical Communications. 2020 ; Vol. 56, No. 54. pp. 7491-7494.

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title = "Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions",

abstract = "The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively. This journal is ",

author = "Kwok, {Chun Leung} and Cheng, {Shun Cheung} and Ho, {Pui Yu} and Yiu, {Shek Man} and MAN, {Wai Lun} and Au, {Vonika Ka Man} and Tsang, {Po Keung} and Leung, {Chi Fai} and Ko, {Chi Chiu} and Marc Robert",

note = "Funding Information: The project was financially supported by the HK Research Grants Council (project number 18300715 and 18301418). Financial support (SGF-23) from EdUHK is also acknowledged.",

year = "2020",

month = jul,

day = "11",

doi = "10.1039/D0CC02604B",

language = "English",

volume = "56",

pages = "7491--7494",

journal = "Chemical Communications",

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Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions. / Kwok, Chun Leung; Cheng, Shun Cheung; Ho, Pui Yu; Yiu, Shek Man; MAN, Wai Lun; Au, Vonika Ka Man; Tsang, Po Keung; Leung, Chi Fai; Ko, Chi Chiu; Robert, Marc.

In: Chemical Communications, Vol. 56, No. 54, 11.07.2020, p. 7491-7494.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions

AU - Kwok, Chun Leung

AU - Cheng, Shun Cheung

AU - Ho, Pui Yu

AU - Yiu, Shek Man

AU - MAN, Wai Lun

AU - Au, Vonika Ka Man

AU - Tsang, Po Keung

AU - Leung, Chi Fai

AU - Ko, Chi Chiu

AU - Robert, Marc

N1 - Funding Information: The project was financially supported by the HK Research Grants Council (project number 18300715 and 18301418). Financial support (SGF-23) from EdUHK is also acknowledged.

PY - 2020/7/11

Y1 - 2020/7/11

N2 - The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively. This journal is

AB - The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino-dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively. This journal is

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U2 - 10.1039/D0CC02604B

DO - 10.1039/D0CC02604B

M3 - Article

C2 - 32497158

AN - SCOPUS:85087751478

VL - 56

SP - 7491

EP - 7494

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 54

ER -

Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine-dioxime catalysts under both aqueous and organic conditions

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