Possible heterogeneous chemistry of hydroxymethanesulfonate (HMS) in northern China winter haze

Shaojie Song*, Meng Gao, Weiqi Xu, Yele Sun*, Douglas R. Worsnop, John T. Jayne, Yuzhong Zhang, Lei Zhu, Mei Li, Zhen Zhou, Chunlei Cheng, Yibing Lv, Ying Wang, Wei Peng, Xiaobin Xu, Nan Lin, Yuxuan Wang, Shuxiao Wang, J. William Munger, Daniel J. JacobMichael B. McElroy*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The chemical mechanisms responsible for rapid sulfate production, an important driver of winter haze formation in northern China, remain unclear. Here, we propose a potentially important heterogeneous hydroxymethanesulfonate (HMS) chemical mechanism. Through analyzing field measurements with aerosol mass spectrometry, we show evidence for a possible significant existence in haze aerosols of organosulfur primarily as HMS, misidentified as sulfate in previous observations. We estimate that HMS can account for up to about one-third of the sulfate concentrations unexplained by current air quality models. Heterogeneous production of HMS by SO2 and formaldehyde is favored under northern China winter haze conditions due to high aerosol water content, moderately acidic pH values, high gaseous precursor levels, and low temperature. These analyses identify an unappreciated importance of formaldehyde in secondary aerosol formation and call for more research on sources and on the chemistry of formaldehyde in northern China winter.
Original languageUndefined/Unknown
Pages (from-to)1357-1371
Number of pages15
JournalAtmospheric Chemistry and Physics
Volume19
Issue number2
DOIs
Publication statusPublished - 1 Feb 2019

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