Pollutants from primary sources dominate the oxidative potential of water-soluble PM_2.5 in Hong Kong in terms of dithiothreitol (DTT) consumption and hydroxyl radical production

Increasing scientific findings show that the adverse health effects of PM_2.5 are related not only to its mass but also PM_2.5 sources and chemical compositions. Here, we conducted a comprehensive characterization and source apportionment of oxidative potential (OP) of water-soluble PM_2.5 collected in Hong Kong for one year. Two OP indicators, namely dithiothreitol (DTT) consumption and ∙OH formation, were quantified. Six PM_2.5 sources, i.e. secondary sulfate, biomass burning, secondary organic aerosol (SOA), vehicle emissions, marine vessels, and a metal-related factor, were apportioned and identified to be DTT active. The four primary sources accounted for 83.5% of DTT activity of water-soluble PM_2.5, with the metal-related factor and marine vessels as the leading contributors. However, only three sources, i.e. metal-related factor, vehicle emissions, and SOA, showed ∙OH generation ability, with a predominant contribution of 96.2% from the two primary sources, especially the metal-related factor (84.5%). Based on the source apportionment results, we further evaluate the intrinsic OP of water-soluble PM_2.5 from each source. Marine vessels exhibited the highest intrinsic DTT activity; while metal-related factor was most effective in ∙OH generation.