@article{3e67ce4665ec4807908ede31af4c5aa7,
title = "Photofunctionality in Porphyrin-Hybridized Bis(dipyrrinato)zinc(II) Complex Micro- and Nanosheets",
abstract = "New bis(dipyrrinato)zinc(II) complex micro- and nanosheets containing zinc(II) porphyrin (N2) are synthesized. A liquid/liquid interface method between dipyrrin porphyrin ligand L2 and zinc acetate produces N2 with a large domain size. N2 can be layered quantitatively onto a flat substrate by a modified Langmuir–Sch{\"a}fer method. N2 deposited on a SnO2 electrode functions as a photoanode for a photoelectric conversion system. The photoresponse of N2 covers the whole visible wavelength range (400–650 nm), with a maximum quantum efficiency of more than twice that of a bis(dipyrrinato)zinc(II) complex nanosheet without porphyrin.",
keywords = "metal–organic frameworks (MOFs), nanosheets, photovoltaics, porphyrins, zinc",
author = "Ryota Sakamoto and Toshiki Yagi and Ken Hoshiko and Shinpei Kusaka and Ryota Matsuoka and Hiroaki Maeda and Zheng Liu and Qian Liu and Wong, {Wai Yeung} and Hiroshi Nishihara",
note = "Funding Information: This work was supported by JST-PRESTO “Hyper-nano-space design toward Innovative Functionality” (To R.S.) and JST-CREST “Development of Atomic or Molecular Two-Dimensional Functional Films and Creation of Fundamental Technologies for Their Applications” (to H.N.). We also acknowledge JSPS KAKENHI Grant Numbers JP25107003, JP26620039, JP26220801, JP26708005, JP15H00862, JP16H00900, JP16H00957. W.-Y.W. thanks the Hong Kong Research Grants Council (HKBU 12302114), Areas of Excellence Scheme of HKSAR (AoE/P-03/08), National Natural Science Foundation of China (Project Nos. 51573151 and 91333206), Science, Technology, and Innovation Committee of Shenzhen Municipality (JCYJ20140419130507116), Hong Kong Baptist University (FRG2/13-14/083) and the Hong Kong Polytechnic University for financial support and Ms. Elizabeth Law for the Endowed Chair Professorship of Advanced Materials. Publisher copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2017",
month = mar,
day = "20",
doi = "10.1002/anie.201611785",
language = "English",
volume = "56",
pages = "3526--3530",
journal = "Angewandte Chemie. International Edition",
issn = "1433-7851",
publisher = "John Wiley & Sons Ltd.",
number = "13",
}
