Permeability and permselectivity of polyphenylenediamine films synthesized at a palladium disk electrode

Yi Qing Dai; Dong Mei Zhou; Kwok Keung Shiu

doi:10.1016/j.electacta.2006.05.010

Permeability and permselectivity of polyphenylenediamine films synthesized at a palladium disk electrode

Yi Qing Dai, Dong Mei Zhou, Kwok Keung Shiu^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

74 Citations (Scopus)

Abstract

Three phenylenediamine isomers (including ortho-, meta- and para-derivatives) were electrochemically polymerized on palladium disk electrodes. The permeability and permselectivity of polyphenylenediamine films for hydrogen peroxide, ascorbic acid, uric acid, acetaminophen, and cysteine were compared. The resulting polyphenylenediamine electrodes showed rapid electrochemical responses to hydrogen peroxide and good anti-fouling ability to possible interferences. Experimental results provide useful information for the fabrication of membrane-based enzyme electrodes.

Original language	English
Pages (from-to)	297-303
Number of pages	7
Journal	Electrochimica Acta
Volume	52
Issue number	1
DOIs	https://doi.org/10.1016/j.electacta.2006.05.010
Publication status	Published - 5 Oct 2006

Scopus Subject Areas

General Chemical Engineering
Electrochemistry

User-Defined Keywords

Electropolymerized films
Hydrogen peroxide
Permeability
Permselectivity
Phenylenediamine isomers

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10.1016/j.electacta.2006.05.010

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title = "Permeability and permselectivity of polyphenylenediamine films synthesized at a palladium disk electrode",

abstract = "Three phenylenediamine isomers (including ortho-, meta- and para-derivatives) were electrochemically polymerized on palladium disk electrodes. The permeability and permselectivity of polyphenylenediamine films for hydrogen peroxide, ascorbic acid, uric acid, acetaminophen, and cysteine were compared. The resulting polyphenylenediamine electrodes showed rapid electrochemical responses to hydrogen peroxide and good anti-fouling ability to possible interferences. Experimental results provide useful information for the fabrication of membrane-based enzyme electrodes.",

keywords = "Electropolymerized films, Hydrogen peroxide, Permeability, Permselectivity, Phenylenediamine isomers",

author = "Dai, {Yi Qing} and Zhou, {Dong Mei} and Shiu, {Kwok Keung}",

note = "Funding Information: This work was partially supported by the Faculty Research Grants of Hong Kong Baptist University.",

year = "2006",

month = oct,

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doi = "10.1016/j.electacta.2006.05.010",

language = "English",

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journal = "Electrochimica Acta",

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TY - JOUR

T1 - Permeability and permselectivity of polyphenylenediamine films synthesized at a palladium disk electrode

AU - Dai, Yi Qing

AU - Zhou, Dong Mei

AU - Shiu, Kwok Keung

N1 - Funding Information: This work was partially supported by the Faculty Research Grants of Hong Kong Baptist University.

PY - 2006/10/5

Y1 - 2006/10/5

N2 - Three phenylenediamine isomers (including ortho-, meta- and para-derivatives) were electrochemically polymerized on palladium disk electrodes. The permeability and permselectivity of polyphenylenediamine films for hydrogen peroxide, ascorbic acid, uric acid, acetaminophen, and cysteine were compared. The resulting polyphenylenediamine electrodes showed rapid electrochemical responses to hydrogen peroxide and good anti-fouling ability to possible interferences. Experimental results provide useful information for the fabrication of membrane-based enzyme electrodes.

AB - Three phenylenediamine isomers (including ortho-, meta- and para-derivatives) were electrochemically polymerized on palladium disk electrodes. The permeability and permselectivity of polyphenylenediamine films for hydrogen peroxide, ascorbic acid, uric acid, acetaminophen, and cysteine were compared. The resulting polyphenylenediamine electrodes showed rapid electrochemical responses to hydrogen peroxide and good anti-fouling ability to possible interferences. Experimental results provide useful information for the fabrication of membrane-based enzyme electrodes.

KW - Electropolymerized films

KW - Hydrogen peroxide

KW - Permeability

KW - Permselectivity

KW - Phenylenediamine isomers

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U2 - 10.1016/j.electacta.2006.05.010

DO - 10.1016/j.electacta.2006.05.010

M3 - Journal article

AN - SCOPUS:33748534784

SN - 0013-4686

VL - 52

SP - 297

EP - 303

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 1

ER -

Permeability and permselectivity of polyphenylenediamine films synthesized at a palladium disk electrode

Abstract

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