Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

Qian Feng Zhang, Florence K.M. Cheung, Wai Yeung WONG, Ian D. Williams, Wa Hung Leung*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.

Original languageEnglish
Pages (from-to)3777-3781
Number of pages5
JournalOrganometallics
Volume20
Issue number17
DOIs
Publication statusPublished - 20 Aug 2001

Scopus Subject Areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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