Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

Qian Feng Zhang; Florence K.M. Cheung; Wai Yeung Wong; Ian D. Williams; Wa Hung Leung

doi:10.1021/om010054x

Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

Qian Feng Zhang, Florence K.M. Cheung, Wai Yeung Wong, Ian D. Williams, Wa Hung Leung^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

37 Citations (Scopus)

Abstract

Treatment of [Cp*Ru(NO)Cl₂] (Cp* = η⁵-C₅Me₅) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C₆F₄H or Ph) affords [Cp*Ru(NO)(QAr)₂]. Interactions of [Cp*Ru(NO)(SC₆F₄H)₂] with PR₃ (R = Ph or Me) give [Cp*Ru(PR₃)₂(SC₆ F₄H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC₆F₄H)₂] and [Cp*Ru(PMe₃)₂(SC₆F₄H)] have been determined. Treatment of [Cp*Ru(MeCN)₃][PF₆] with HN[SeP(i-Pr)₂]₂ affords a novel Cp*Ru(IV) complex, [Cp*Ru{η²-Se₂P(i-Pr)₂} {η²-SeP(i-Pr)₂}][PF₆], which has been characterized by X-ray crystallography.

Original language	English
Pages (from-to)	3777-3781
Number of pages	5
Journal	Organometallics
Volume	20
Issue number	17
DOIs	https://doi.org/10.1021/om010054x
Publication status	Published - 20 Aug 2001

Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{0a69880b97e44c0eb6dc75c8f1985d38,

title = "Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands",

abstract = "Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.",

author = "Zhang, {Qian Feng} and Cheung, {Florence K.M.} and Wong, {Wai Yeung} and Williams, {Ian D.} and Leung, {Wa Hung}",

note = "The financial support from the Hong Kong University of Science and Technology and the Hong Kong Research Grants Council is gratefully acknowledged. We thank Dr. Zhenyang Lin for helpful discussions. ",

year = "2001",

month = aug,

day = "20",

doi = "10.1021/om010054x",

language = "English",

volume = "20",

pages = "3777--3781",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

AU - Zhang, Qian Feng

AU - Cheung, Florence K.M.

AU - Wong, Wai Yeung

AU - Williams, Ian D.

AU - Leung, Wa Hung

N1 - The financial support from the Hong Kong University of Science and Technology and the Hong Kong Research Grants Council is gratefully acknowledged. We thank Dr. Zhenyang Lin for helpful discussions.

PY - 2001/8/20

Y1 - 2001/8/20

N2 - Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.

AB - Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.

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U2 - 10.1021/om010054x

DO - 10.1021/om010054x

M3 - Journal article

AN - SCOPUS:0035921552

SN - 0276-7333

VL - 20

SP - 3777

EP - 3781

JO - Organometallics

JF - Organometallics

IS - 17

ER -

Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

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