Palladium-catalyzed intramolecular dehydrogenative coupling of BH and OH: synthesis of carborane-fused benzoxaboroles

Chun Xiao Cui; Jie Zhang; Zaozao Qiu; Zuowei Xie

doi:10.1039/c9dt04553h

Palladium-catalyzed intramolecular dehydrogenative coupling of BH and OH: synthesis of carborane-fused benzoxaboroles

Chun Xiao Cui
, Jie Zhang
, Zaozao Qiu^*
, Zuowei Xie^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

34 Citations (Scopus)

Abstract

A Pd-catalyzed intramolecular dehydrogenative coupling of BH and OH for the construction of cage B–O bonds has been developed, leading to a new class of 1,3- and 1,4-o-carboranobenzoxaborole derivatives. This represents a new route to C,B-carborane-fused heterocycles.

Original language	English
Pages (from-to)	1380-1383
Number of pages	4
Journal	Dalton Transactions
Volume	49
Issue number	5
Early online date	3 Jan 2020
DOIs	https://doi.org/10.1039/c9dt04553h
Publication status	Published - 7 Feb 2020

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10.1039/c9dt04553h

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title = "Palladium-catalyzed intramolecular dehydrogenative coupling of BH and OH: synthesis of carborane-fused benzoxaboroles",

abstract = "A Pd-catalyzed intramolecular dehydrogenative coupling of BH and OH for the construction of cage B–O bonds has been developed, leading to a new class of 1,3- and 1,4-o-carboranobenzoxaborole derivatives. This represents a new route to C,B-carborane-fused heterocycles.",

author = "Cui, \{Chun Xiao\} and Jie Zhang and Zaozao Qiu and Zuowei Xie",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2020. Funding Information: This work was supported by grants from the National Natural Science Foundation of China (no. 21772223 to Z. Q.), the Science and Technology Commission of Shanghai Municipality (no. 18590760800), the Chinese Academy of Sciences, and the Hong Kong Research Grants Council (no. 14305017 and N\_CUHK402/18).",

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T2 - synthesis of carborane-fused benzoxaboroles

AU - Cui, Chun Xiao

AU - Zhang, Jie

AU - Qiu, Zaozao

AU - Xie, Zuowei

N1 - Publisher Copyright: © The Royal Society of Chemistry 2020. Funding Information: This work was supported by grants from the National Natural Science Foundation of China (no. 21772223 to Z. Q.), the Science and Technology Commission of Shanghai Municipality (no. 18590760800), the Chinese Academy of Sciences, and the Hong Kong Research Grants Council (no. 14305017 and N_CUHK402/18).

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Y1 - 2020/2/7

N2 - A Pd-catalyzed intramolecular dehydrogenative coupling of BH and OH for the construction of cage B–O bonds has been developed, leading to a new class of 1,3- and 1,4-o-carboranobenzoxaborole derivatives. This represents a new route to C,B-carborane-fused heterocycles.

AB - A Pd-catalyzed intramolecular dehydrogenative coupling of BH and OH for the construction of cage B–O bonds has been developed, leading to a new class of 1,3- and 1,4-o-carboranobenzoxaborole derivatives. This represents a new route to C,B-carborane-fused heterocycles.

UR - https://www.scopus.com/pages/publications/85079078204

U2 - 10.1039/c9dt04553h

DO - 10.1039/c9dt04553h

M3 - Journal article

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EP - 1383

JO - Dalton Transactions

JF - Dalton Transactions

IS - 5

ER -

Palladium-catalyzed intramolecular dehydrogenative coupling of BH and OH: synthesis of carborane-fused benzoxaboroles

Abstract

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