P-P orbital interaction via magnesium isovalent doping enhances optoelectronic properties of halide perovskites

Feng Qian; Jue Gong; Mingyu Hu; Chunyu Ge; Nitin P. Padture; Yuanyuan Zhou; Jing Feng

doi:10.1039/d0cc02150d

P-P orbital interaction via magnesium isovalent doping enhances optoelectronic properties of halide perovskites

Feng Qian, Jue Gong, Mingyu Hu, Chunyu Ge, Nitin P. Padture^*, Yuanyuan Zhou^*, Jing Feng^*

^*Corresponding author for this work

Department of Physics

Research output: Contribution to journal › Journal article › peer-review

3 Citations (Scopus)

Abstract

p–p orbital interaction through Mg(II) isovalent doping in methylammonium lead chloride perovskite significantly enhances the electronic properties while not affecting the optical bandgap. This chemical behaviour shows promising applications to optoelectronic devices.

Original language	English
Pages (from-to)	15639-15642
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	100
Early online date	7 Dec 2020
DOIs	https://doi.org/10.1039/d0cc02150d
Publication status	Published - 21 Dec 2020

Scopus Subject Areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc02150d

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@article{e3dec0db048541c2a41aed2e352e16b8,

title = "P-P orbital interaction via magnesium isovalent doping enhances optoelectronic properties of halide perovskites",

abstract = "p–p orbital interaction through Mg(II) isovalent doping in methylammonium lead chloride perovskite significantly enhances the electronic properties while not affecting the optical bandgap. This chemical behaviour shows promising applications to optoelectronic devices.",

author = "Feng Qian and Jue Gong and Mingyu Hu and Chunyu Ge and Padture, {Nitin P.} and Yuanyuan Zhou and Jing Feng",

note = "Funding Information: This research performed at Kunming University of Science and Technology is supported by the National Key R&D Program of China (No. 2019YFB1503200), the National Natural Science Foundation of China (grant No. 11504146 and No. 51762028), and Rare Metal Material Genetic Engineering Project of Yunnan Province (grant no. 2018ZE019). The research performed at Brown University is supported by the US National Science Foundation (grant No. OIA-1538893).",

year = "2020",

month = dec,

day = "21",

doi = "10.1039/d0cc02150d",

language = "English",

volume = "56",

pages = "15639--15642",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - P-P orbital interaction via magnesium isovalent doping enhances optoelectronic properties of halide perovskites

AU - Qian, Feng

AU - Gong, Jue

AU - Hu, Mingyu

AU - Ge, Chunyu

AU - Padture, Nitin P.

AU - Zhou, Yuanyuan

AU - Feng, Jing

N1 - Funding Information: This research performed at Kunming University of Science and Technology is supported by the National Key R&D Program of China (No. 2019YFB1503200), the National Natural Science Foundation of China (grant No. 11504146 and No. 51762028), and Rare Metal Material Genetic Engineering Project of Yunnan Province (grant no. 2018ZE019). The research performed at Brown University is supported by the US National Science Foundation (grant No. OIA-1538893).

PY - 2020/12/21

Y1 - 2020/12/21

N2 - p–p orbital interaction through Mg(II) isovalent doping in methylammonium lead chloride perovskite significantly enhances the electronic properties while not affecting the optical bandgap. This chemical behaviour shows promising applications to optoelectronic devices.

AB - p–p orbital interaction through Mg(II) isovalent doping in methylammonium lead chloride perovskite significantly enhances the electronic properties while not affecting the optical bandgap. This chemical behaviour shows promising applications to optoelectronic devices.

UR - http://www.scopus.com/inward/record.url?scp=85098555735&partnerID=8YFLogxK

U2 - 10.1039/d0cc02150d

DO - 10.1039/d0cc02150d

M3 - Journal article

C2 - 33283795

AN - SCOPUS:85098555735

SN - 1359-7345

VL - 56

SP - 15639

EP - 15642

JO - Chemical Communications

JF - Chemical Communications

IS - 100

ER -

P-P orbital interaction via magnesium isovalent doping enhances optoelectronic properties of halide perovskites

Abstract

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