Oxygen evolution from BF3/MnO4-

Shek Man Yiu; Wai Lun Man; Xin Wang; William W.Y. Lam; Siu Mui Ng; Hoi Ki Kwong; Kai Chung Lau; Tai Chu Lau

doi:10.1039/c1cc00019e

Oxygen evolution from BF₃/MnO₄^-

Shek Man Yiu
, Wai Lun Man
, Xin Wang
, William W.Y. Lam
, Siu Mui Ng
, Hoi Ki Kwong
, Kai Chung Lau^*
, Tai Chu Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

15 Citations (Scopus)

Abstract

MnO₄^- is activated by BF₃ to undergo intramolecular coupling of two oxo ligands to generate O₂. DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO₂(OBF₃)₂]^- to the O⋯O coupling transition state.

Original language	English
Pages (from-to)	4159-4161
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	14
Early online date	28 Feb 2011
DOIs	https://doi.org/10.1039/c1cc00019e
Publication status	Published - 14 Apr 2011

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title = "Oxygen evolution from BF3/MnO4-",

abstract = "MnO4- is activated by BF3 to undergo intramolecular coupling of two oxo ligands to generate O2. DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO2(OBF3)2]- to the O⋯O coupling transition state.",

author = "Yiu, \{Shek Man\} and Man, \{Wai Lun\} and Xin Wang and Lam, \{William W.Y.\} and Ng, \{Siu Mui\} and Kwong, \{Hoi Ki\} and Lau, \{Kai Chung\} and Lau, \{Tai Chu\}",

note = "The work described in this communication was supported by the Hong Kong University Grants Committee Area of Excellence Scheme (AoE/P-03-08) and General Research Fund (CityU 101408). ",

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doi = "10.1039/c1cc00019e",

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journal = "Chemical Communications",

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T1 - Oxygen evolution from BF3/MnO4-

AU - Yiu, Shek Man

AU - Man, Wai Lun

AU - Wang, Xin

AU - Lam, William W.Y.

AU - Ng, Siu Mui

AU - Kwong, Hoi Ki

AU - Lau, Kai Chung

AU - Lau, Tai Chu

N1 - The work described in this communication was supported by the Hong Kong University Grants Committee Area of Excellence Scheme (AoE/P-03-08) and General Research Fund (CityU 101408).

PY - 2011/4/14

Y1 - 2011/4/14

N2 - MnO4- is activated by BF3 to undergo intramolecular coupling of two oxo ligands to generate O2. DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO2(OBF3)2]- to the O⋯O coupling transition state.

AB - MnO4- is activated by BF3 to undergo intramolecular coupling of two oxo ligands to generate O2. DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO2(OBF3)2]- to the O⋯O coupling transition state.

UR - https://www.scopus.com/pages/publications/79954992139

U2 - 10.1039/c1cc00019e

DO - 10.1039/c1cc00019e

M3 - Journal article

C2 - 21359340

SN - 1359-7345

VL - 47

SP - 4159

EP - 4161

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Oxygen evolution from BF₃/MnO₄^-

Abstract

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