Oxidation of hydroquinones by a (salen)ruthenium(VI) nitrido complex

Jianhui Xie; Po Kam Lo; William W.Y. Lam; Wai Lun Man; Li Ma; Shek Man Yiu; Kai Chung Lau; Tai Chu Lau

doi:10.1039/c6cc06231h

Oxidation of hydroquinones by a (salen)ruthenium(VI) nitrido complex

Jianhui Xie
, Po Kam Lo
, William W.Y. Lam
, Wai Lun Man
, Li Ma
, Shek Man Yiu
, Kai Chung Lau^*
, Tai Chu Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

8 Citations (Scopus)

Abstract

Hydroquinone is readily oxidized by a (salen)ruthenium(vi) nitrido complex in the presence of pyridine to give benzoquinone. Experimental and computational studies suggest that the reaction occurs via a novel mechanism that involves an initial electrophilic attack at the aromatic ring of the hydroquinone by the nitrido ligand.

Original language	English
Pages (from-to)	11430-11433
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	76
Early online date	19 Aug 2016
DOIs	https://doi.org/10.1039/c6cc06231h
Publication status	Published - 1 Oct 2016

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title = "Oxidation of hydroquinones by a (salen)ruthenium(VI) nitrido complex",

abstract = "Hydroquinone is readily oxidized by a (salen)ruthenium(vi) nitrido complex in the presence of pyridine to give benzoquinone. Experimental and computational studies suggest that the reaction occurs via a novel mechanism that involves an initial electrophilic attack at the aromatic ring of the hydroquinone by the nitrido ligand.",

author = "Jianhui Xie and Lo, \{Po Kam\} and Lam, \{William W.Y.\} and Man, \{Wai Lun\} and Li Ma and Yiu, \{Shek Man\} and Lau, \{Kai Chung\} and Lau, \{Tai Chu\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

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doi = "10.1039/c6cc06231h",

language = "English",

volume = "52",

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T1 - Oxidation of hydroquinones by a (salen)ruthenium(VI) nitrido complex

AU - Xie, Jianhui

AU - Lo, Po Kam

AU - Lam, William W.Y.

AU - Man, Wai Lun

AU - Ma, Li

AU - Yiu, Shek Man

AU - Lau, Kai Chung

AU - Lau, Tai Chu

PY - 2016/10/1

Y1 - 2016/10/1

N2 - Hydroquinone is readily oxidized by a (salen)ruthenium(vi) nitrido complex in the presence of pyridine to give benzoquinone. Experimental and computational studies suggest that the reaction occurs via a novel mechanism that involves an initial electrophilic attack at the aromatic ring of the hydroquinone by the nitrido ligand.

AB - Hydroquinone is readily oxidized by a (salen)ruthenium(vi) nitrido complex in the presence of pyridine to give benzoquinone. Experimental and computational studies suggest that the reaction occurs via a novel mechanism that involves an initial electrophilic attack at the aromatic ring of the hydroquinone by the nitrido ligand.

UR - https://www.scopus.com/pages/publications/84987924244

U2 - 10.1039/c6cc06231h

DO - 10.1039/c6cc06231h

M3 - Journal article

AN - SCOPUS:84987924244

SN - 1359-7345

VL - 52

SP - 11430

EP - 11433

JO - Chemical Communications

JF - Chemical Communications

IS - 76

ER -

Oxidation of hydroquinones by a (salen)ruthenium(VI) nitrido complex

Abstract

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