Oxadisilole fused triptycene and extended triptycene: Precursors of triptycyne and extended triptycyne

Bao Jian Pei; Wing Hong Chan; Albert W.M. Lee

doi:10.1021/jo1016025

Oxadisilole fused triptycene and extended triptycene: Precursors of triptycyne and extended triptycyne

Bao Jian Pei
, Wing Hong Chan
, Albert W.M. Lee

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

16 Citations (Scopus)

Abstract

With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized.

Original language	English
Pages (from-to)	7332-7337
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	75
Issue number	21
DOIs	https://doi.org/10.1021/jo1016025
Publication status	Published - 5 Nov 2010

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10.1021/jo1016025

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title = "Oxadisilole fused triptycene and extended triptycene: Precursors of triptycyne and extended triptycyne",

abstract = "With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized.",

author = "Pei, \{Bao Jian\} and Chan, \{Wing Hong\} and Lee, \{Albert W.M.\}",

note = "Financial support from the Hong Kong Research Grants Council (HKBU 201307) is gratefully acknowledged. ",

year = "2010",

month = nov,

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doi = "10.1021/jo1016025",

language = "English",

volume = "75",

pages = "7332--7337",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Oxadisilole fused triptycene and extended triptycene

T2 - Precursors of triptycyne and extended triptycyne

AU - Pei, Bao Jian

AU - Chan, Wing Hong

AU - Lee, Albert W.M.

N1 - Financial support from the Hong Kong Research Grants Council (HKBU 201307) is gratefully acknowledged.

PY - 2010/11/5

Y1 - 2010/11/5

N2 - With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized.

AB - With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized.

UR - https://www.scopus.com/pages/publications/78049501337

U2 - 10.1021/jo1016025

DO - 10.1021/jo1016025

M3 - Journal article

AN - SCOPUS:78049501337

SN - 0022-3263

VL - 75

SP - 7332

EP - 7337

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Oxadisilole fused triptycene and extended triptycene: Precursors of triptycyne and extended triptycyne

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