Oxadisilole fused triptycene and extended triptycene: Precursors of triptycyne and extended triptycyne

Bao Jian Pei; Wing Hong CHAN; Albert W M LEE

doi:10.1021/jo1016025

Oxadisilole fused triptycene and extended triptycene: Precursors of triptycyne and extended triptycyne

Bao Jian Pei, Wing Hong CHAN, Albert W M LEE

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

14 Citations (Scopus)

Abstract

With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized.

Original language	English
Pages (from-to)	7332-7337
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	75
Issue number	21
DOIs	https://doi.org/10.1021/jo1016025
Publication status	Published - 5 Nov 2010

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Organic Chemistry

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title = "Oxadisilole fused triptycene and extended triptycene: Precursors of triptycyne and extended triptycyne",

abstract = "With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized.",

author = "Pei, {Bao Jian} and CHAN, {Wing Hong} and LEE, {Albert W M}",

note = "Financial support from the Hong Kong Research Grants Council (HKBU 201307) is gratefully acknowledged. ",

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T2 - Precursors of triptycyne and extended triptycyne

AU - Pei, Bao Jian

AU - CHAN, Wing Hong

AU - LEE, Albert W M

N1 - Financial support from the Hong Kong Research Grants Council (HKBU 201307) is gratefully acknowledged.

PY - 2010/11/5

Y1 - 2010/11/5

N2 - With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized.

AB - With benzobisoxadisilole 1 as a 1,4-benzdiyne equivalent, oxadisilole fused triptycene 5 and extended triptycene 6 were synthesized. Triptycenes 5 and 6 are new precursors of triptycyne 7 and extended triptycyne 8 respectively via the phenyliodination/fluoride induced elimination protocol. Using these two arynes, a series of triptycene derivatives were synthesized.

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U2 - 10.1021/jo1016025

DO - 10.1021/jo1016025

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Oxadisilole fused triptycene and extended triptycene: Precursors of triptycyne and extended triptycyne

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