Organocatalytic construction of axially chiral phosphorus-containing arylpyrazoles

Shihui Luo; Jun (Joelle) Wang

doi:10.1016/j.checat.2023.100579

Organocatalytic construction of axially chiral phosphorus-containing arylpyrazoles

Shihui Luo, Jun (Joelle) Wang^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

Abstract

In Angewandte Chemie, Wang, Song, and co-workers report a novel and practical organocatalysis methodology for accessing axially chiral pyrazole-based phosphorus scaffolds. They induced the central-to-axial chirality conversion in Huisgen-type cycloaddition by using a dipeptide-phosphonium salt catalyst under very low catalyst loading (1 mol %).

Original language	English
Article number	100579
Journal	Chem Catalysis
Volume	3
Issue number	3
DOIs	https://doi.org/10.1016/j.checat.2023.100579
Publication status	Published - 16 Mar 2023

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title = "Organocatalytic construction of axially chiral phosphorus-containing arylpyrazoles",

abstract = "In Angewandte Chemie, Wang, Song, and co-workers report a novel and practical organocatalysis methodology for accessing axially chiral pyrazole-based phosphorus scaffolds. They induced the central-to-axial chirality conversion in Huisgen-type cycloaddition by using a dipeptide-phosphonium salt catalyst under very low catalyst loading (1 mol %).",

author = "Shihui Luo and Wang, {Jun (Joelle)}",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier Inc.",

year = "2023",

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day = "16",

doi = "10.1016/j.checat.2023.100579",

language = "English",

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AU - Luo, Shihui

AU - Wang, Jun (Joelle)

PY - 2023/3/16

Y1 - 2023/3/16

N2 - In Angewandte Chemie, Wang, Song, and co-workers report a novel and practical organocatalysis methodology for accessing axially chiral pyrazole-based phosphorus scaffolds. They induced the central-to-axial chirality conversion in Huisgen-type cycloaddition by using a dipeptide-phosphonium salt catalyst under very low catalyst loading (1 mol %).

AB - In Angewandte Chemie, Wang, Song, and co-workers report a novel and practical organocatalysis methodology for accessing axially chiral pyrazole-based phosphorus scaffolds. They induced the central-to-axial chirality conversion in Huisgen-type cycloaddition by using a dipeptide-phosphonium salt catalyst under very low catalyst loading (1 mol %).

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U2 - 10.1016/j.checat.2023.100579

DO - 10.1016/j.checat.2023.100579

M3 - Journal article

AN - SCOPUS:85149822762

SN - 2667-1107

VL - 3

JO - Chem Catalysis

JF - Chem Catalysis

IS - 3

M1 - 100579

ER -

Organocatalytic construction of axially chiral phosphorus-containing arylpyrazoles

Abstract

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