Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(iii) complexes

Dale Lawson; Alessandro Barge; Enzo Terreno; David Parker; Silvio Aime; Mauro Botta

doi:10.1039/c4dt02971b

Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(iii) complexes

Dale Lawson
, Alessandro Barge
, Enzo Terreno
, David Parker
, Silvio Aime
, Mauro Botta^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

10 Citations (Scopus)

Abstract

Using recognition moieties that bind to the inner co-ordination sphere of a monomeric DO3A-type di-aqua complex, dimeric poly(aminocarboxylate) gadolinium(iii) compounds can be formed with greatly enhanced relaxivities, arising from optimized contributions of inner- and second spheres of hydration.

Original language	English
Pages (from-to)	4910-4917
Number of pages	8
Journal	Dalton Transactions
Volume	44
Issue number	11
Early online date	7 Nov 2014
DOIs	https://doi.org/10.1039/c4dt02971b
Publication status	Published - 21 Mar 2015

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title = "Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(iii) complexes",

abstract = "Using recognition moieties that bind to the inner co-ordination sphere of a monomeric DO3A-type di-aqua complex, dimeric poly(aminocarboxylate) gadolinium(iii) compounds can be formed with greatly enhanced relaxivities, arising from optimized contributions of inner- and second spheres of hydration.",

author = "Dale Lawson and Alessandro Barge and Enzo Terreno and David Parker and Silvio Aime and Mauro Botta",

note = "This work was supported by MIUR (PRIN 2012). MB thanks financial support of the “Compagnia di San Paolo” (CSP-2012 NANOPROGLY Project). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

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T1 - Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(iii) complexes

AU - Lawson, Dale

AU - Barge, Alessandro

AU - Terreno, Enzo

AU - Parker, David

AU - Aime, Silvio

AU - Botta, Mauro

PY - 2015/3/21

Y1 - 2015/3/21

N2 - Using recognition moieties that bind to the inner co-ordination sphere of a monomeric DO3A-type di-aqua complex, dimeric poly(aminocarboxylate) gadolinium(iii) compounds can be formed with greatly enhanced relaxivities, arising from optimized contributions of inner- and second spheres of hydration.

AB - Using recognition moieties that bind to the inner co-ordination sphere of a monomeric DO3A-type di-aqua complex, dimeric poly(aminocarboxylate) gadolinium(iii) compounds can be formed with greatly enhanced relaxivities, arising from optimized contributions of inner- and second spheres of hydration.

UR - https://www.scopus.com/pages/publications/84924301148

U2 - 10.1039/c4dt02971b

DO - 10.1039/c4dt02971b

M3 - Journal article

C2 - 25411928

AN - SCOPUS:84924301148

SN - 1477-9226

VL - 44

SP - 4910

EP - 4917

JO - Dalton Transactions

JF - Dalton Transactions

IS - 11

ER -

Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(iii) complexes

Abstract

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