One-step synthesis of cyclohexanone from benzene with O2/H 2 catalyzed by ruthenium diaminodiphosphine complex

Wei Xiong Pan; Rick W K WONG; Xian Qing Qiu; Fu Wa LEE

doi:10.1023/b:catl.0000011080.03035.eb

One-step synthesis of cyclohexanone from benzene with O₂/H ₂ catalyzed by ruthenium diaminodiphosphine complex

Wei Xiong Pan, Rick W K WONG^*, Xian Qing Qiu, Fu Wa LEE

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

4 Citations (Scopus)

Abstract

Cyclohexanone can be one-step synthesized from benzene catalyzed by a ruthenium diaminodiphosphine complex with 65% selectivity (35% phenol as by-product) and TOF = 63 h^-1 at 130°C and 5 MPa (O ₂/H₂ = 1) pressure. chemical equation presented This shows that hydroxylation (oxidation) and hydrogenation (reduction), which normally required totally noncompatible conditions and catalysts, can proceed in a "one-pot" manner by using one metal complex catalyst.

Original language	English
Pages (from-to)	25-27
Number of pages	3
Journal	Catalysis Letters
Volume	92
Issue number	1-2
DOIs	https://doi.org/10.1023/b:catl.0000011080.03035.eb
Publication status	Published - Jan 2004

User-Defined Keywords

Cyclohexanone
One-step synthesis
Ru complex

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title = "One-step synthesis of cyclohexanone from benzene with O2/H 2 catalyzed by ruthenium diaminodiphosphine complex",

abstract = "Cyclohexanone can be one-step synthesized from benzene catalyzed by a ruthenium diaminodiphosphine complex with 65% selectivity (35% phenol as by-product) and TOF = 63 h-1 at 130°C and 5 MPa (O 2/H2 = 1) pressure. chemical equation presented This shows that hydroxylation (oxidation) and hydrogenation (reduction), which normally required totally noncompatible conditions and catalysts, can proceed in a {"}one-pot{"} manner by using one metal complex catalyst.",

keywords = "Cyclohexanone, One-step synthesis, Ru complex",

author = "Pan, {Wei Xiong} and WONG, {Rick W K} and Qiu, {Xian Qing} and LEE, {Fu Wa}",

note = "We acknowledge the Hong Kong Baptist University and the Hong Kong Research Grants Council (HKBU 2053/97P) for financial support of this work.",

year = "2004",

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doi = "10.1023/b:catl.0000011080.03035.eb",

language = "English",

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T1 - One-step synthesis of cyclohexanone from benzene with O2/H 2 catalyzed by ruthenium diaminodiphosphine complex

AU - Pan, Wei Xiong

AU - WONG, Rick W K

AU - Qiu, Xian Qing

AU - LEE, Fu Wa

N1 - We acknowledge the Hong Kong Baptist University and the Hong Kong Research Grants Council (HKBU 2053/97P) for financial support of this work.

PY - 2004/1

Y1 - 2004/1

N2 - Cyclohexanone can be one-step synthesized from benzene catalyzed by a ruthenium diaminodiphosphine complex with 65% selectivity (35% phenol as by-product) and TOF = 63 h-1 at 130°C and 5 MPa (O 2/H2 = 1) pressure. chemical equation presented This shows that hydroxylation (oxidation) and hydrogenation (reduction), which normally required totally noncompatible conditions and catalysts, can proceed in a "one-pot" manner by using one metal complex catalyst.

AB - Cyclohexanone can be one-step synthesized from benzene catalyzed by a ruthenium diaminodiphosphine complex with 65% selectivity (35% phenol as by-product) and TOF = 63 h-1 at 130°C and 5 MPa (O 2/H2 = 1) pressure. chemical equation presented This shows that hydroxylation (oxidation) and hydrogenation (reduction), which normally required totally noncompatible conditions and catalysts, can proceed in a "one-pot" manner by using one metal complex catalyst.

KW - Cyclohexanone

KW - One-step synthesis

KW - Ru complex

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U2 - 10.1023/b:catl.0000011080.03035.eb

DO - 10.1023/b:catl.0000011080.03035.eb

M3 - Journal article

AN - SCOPUS:1542274340

SN - 1011-372X

VL - 92

SP - 25

EP - 27

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -

One-step synthesis of cyclohexanone from benzene with O₂/H ₂ catalyzed by ruthenium diaminodiphosphine complex

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