Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Huaishan Wang; Lap Szeto; Wesley Ting Kwok Chan; Ho Lun Yeung; Ka-Leung WONG; Wing Tak Wong

doi:10.1139/v11-132

Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Huaishan Wang, Lap Szeto, Wesley Ting Kwok Chan, Ho Lun Yeung, Ka-Leung WONG, Wing Tak Wong^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

1 Citation (Scopus)

Abstract

Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn ₂(L1) ₂(L2) ₂] _∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn ₂(L1) ₂(L3) ₂] _∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å ³ that occupies 34.1% of the unit cell.

Original language	English
Pages (from-to)	100-107
Number of pages	8
Journal	Canadian Journal of Chemistry
Volume	90
Issue number	1
DOIs	https://doi.org/10.1139/v11-132
Publication status	Published - Jan 2012

Scopus Subject Areas

Catalysis
Chemistry(all)
Organic Chemistry

User-Defined Keywords

1,2-bis(4-pyridyl)hydrazine
Coordination polymer
Hydrogen bond
Interpenetrating polymer
Metal organic framework
Microporous

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10.1139/v11-132

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title = "Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network",

abstract = "Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 {\AA} 3 that occupies 34.1% of the unit cell.",

keywords = "1,2-bis(4-pyridyl)hydrazine, Coordination polymer, Hydrogen bond, Interpenetrating polymer, Metal organic framework, Microporous",

author = "Huaishan Wang and Lap Szeto and Chan, {Wesley Ting Kwok} and Yeung, {Ho Lun} and Ka-Leung WONG and Wong, {Wing Tak}",

year = "2012",

month = jan,

doi = "10.1139/v11-132",

language = "English",

volume = "90",

pages = "100--107",

journal = "Canadian Journal of Chemistry",

issn = "0008-4042",

publisher = "National Research Council of Canada",

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T1 - Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

AU - Wang, Huaishan

AU - Szeto, Lap

AU - Chan, Wesley Ting Kwok

AU - Yeung, Ho Lun

AU - WONG, Ka-Leung

AU - Wong, Wing Tak

PY - 2012/1

Y1 - 2012/1

N2 - Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell.

AB - Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell.

KW - 1,2-bis(4-pyridyl)hydrazine

KW - Coordination polymer

KW - Hydrogen bond

KW - Interpenetrating polymer

KW - Metal organic framework

KW - Microporous

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U2 - 10.1139/v11-132

DO - 10.1139/v11-132

M3 - Journal article

AN - SCOPUS:84855421542

SN - 0008-4042

VL - 90

SP - 100

EP - 107

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

IS - 1

ER -

Novel Zn(II) coordination polymer based on 1,2-bis(4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Abstract

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