Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties

Jing Xiang; Li Hui Jia; Wai Lun Man; Kang Qian; Shek Man Yiu; Gene Hsiang Lee; Shie Ming Peng; Song Gao; Tai Chu Lau

doi:10.1039/c1cc12446c

Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[Ru^III(Q)₂(CN)₂]^- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties

Jing Xiang, Li Hui Jia, Wai Lun Man, Kang Qian, Shek Man Yiu, Gene Hsiang Lee, Shie Ming Peng, Song Gao^*, Tai Chu Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

19 Citations (Scopus)

Abstract

Reaction of [Ru^II(PPh₃)₃Cl₂] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru ^III(Q)₂(CN)₂]^-. It reacts with hydrated CoCl₂ in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.

Original language	English
Pages (from-to)	8694-8696
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	30
Early online date	2 Jul 2011
DOIs	https://doi.org/10.1039/c1cc12446c
Publication status	Published - 14 Aug 2011

Scopus Subject Areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc12446c

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title = "Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties",

abstract = "Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru III(Q)2(CN)2]-. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.",

author = "Jing Xiang and Jia, {Li Hui} and Man, {Wai Lun} and Kang Qian and Yiu, {Shek Man} and Lee, {Gene Hsiang} and Peng, {Shie Ming} and Song Gao and Lau, {Tai Chu}",

year = "2011",

month = aug,

day = "14",

doi = "10.1039/c1cc12446c",

language = "English",

volume = "47",

pages = "8694--8696",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato)

T2 - Synthesis, structures and magnetic properties

AU - Xiang, Jing

AU - Jia, Li Hui

AU - Man, Wai Lun

AU - Qian, Kang

AU - Yiu, Shek Man

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

AU - Gao, Song

AU - Lau, Tai Chu

PY - 2011/8/14

Y1 - 2011/8/14

N2 - Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru III(Q)2(CN)2]-. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.

AB - Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru III(Q)2(CN)2]-. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.

UR - http://www.scopus.com/inward/record.url?scp=79960553532&partnerID=8YFLogxK

U2 - 10.1039/c1cc12446c

DO - 10.1039/c1cc12446c

M3 - Journal article

AN - SCOPUS:79960553532

SN - 1359-7345

VL - 47

SP - 8694

EP - 8696

JO - Chemical Communications

JF - Chemical Communications

IS - 30

ER -

Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[Ru^III(Q)₂(CN)₂]^- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties

Abstract

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