Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties

Jing Xiang, Li Hui Jia, Wai Lun Man, Kang Qian, Shek Man Yiu, Gene Hsiang Lee, Shie Ming Peng, Song Gao*, Tai Chu Lau*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru III(Q)2(CN)2]-. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.

Original languageEnglish
Pages (from-to)8694-8696
Number of pages3
JournalChemical Communications
Volume47
Issue number30
Early online date2 Jul 2011
DOIs
Publication statusPublished - 14 Aug 2011

Scopus Subject Areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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