TY - JOUR
T1 - Novel μ5-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes
AU - Zhao, Liang
AU - Wong, Wai Yeung
AU - Mak, Thomas C.W.
N1 - Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2006/6/14
Y1 - 2006/6/14
N2 - Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained.
AB - Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained.
KW - Argentophilicity
KW - Coordination modes
KW - Coordination polymers
KW - Metal-ligand interactions
KW - Silver complexes
UR - http://www.scopus.com/inward/record.url?scp=33745472161&partnerID=8YFLogxK
U2 - 10.1002/chem.200501449
DO - 10.1002/chem.200501449
M3 - Journal article
AN - SCOPUS:33745472161
SN - 0947-6539
VL - 12
SP - 4865
EP - 4872
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 18
ER -