Novel μ5-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes

Liang Zhao; Wai Yeung WONG; Thomas C.W. Mak

doi:10.1002/chem.200501449

Novel μ₅-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes

Liang Zhao, Wai Yeung WONG, Thomas C.W. Mak^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

Novel μ₅-η¹,η¹, η¹,η¹,η² and μ₅- η¹,η¹,η¹,η², η² coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag₅ baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained.

Original language	English
Pages (from-to)	4865-4872
Number of pages	8
Journal	Chemistry - A European Journal
Volume	12
Issue number	18
DOIs	https://doi.org/10.1002/chem.200501449
Publication status	Published - 14 Jun 2006

Scopus Subject Areas

Catalysis
Organic Chemistry

User-Defined Keywords

Argentophilicity
Coordination modes
Coordination polymers
Metal-ligand interactions
Silver complexes

Access to Document

10.1002/chem.200501449

Cite this

@article{058dee531fba4ec9a9a772fe5a250b77,

title = "Novel μ5-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes",

abstract = "Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained.",

keywords = "Argentophilicity, Coordination modes, Coordination polymers, Metal-ligand interactions, Silver complexes",

author = "Liang Zhao and WONG, {Wai Yeung} and Mak, {Thomas C.W.}",

year = "2006",

month = jun,

day = "14",

doi = "10.1002/chem.200501449",

language = "English",

volume = "12",

pages = "4865--4872",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "18",

}

TY - JOUR

T1 - Novel μ5-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes

AU - Zhao, Liang

AU - WONG, Wai Yeung

AU - Mak, Thomas C.W.

PY - 2006/6/14

Y1 - 2006/6/14

N2 - Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained.

AB - Novel μ5-η1,η1, η1,η1,η2 and μ5- η1,η1,η1,η2, η2 coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into σ, π and mixed (σ,π) types. With the consistent square-pyramidal capping Ag5 baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained.

KW - Argentophilicity

KW - Coordination modes

KW - Coordination polymers

KW - Metal-ligand interactions

KW - Silver complexes

UR - http://www.scopus.com/inward/record.url?scp=33745472161&partnerID=8YFLogxK

U2 - 10.1002/chem.200501449

DO - 10.1002/chem.200501449

M3 - Article

AN - SCOPUS:33745472161

SN - 0947-6539

VL - 12

SP - 4865

EP - 4872

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 18

ER -