N=N bond cleavage in diazirines by a cyclic diborane(4) compound

Minling Zhong; Jie Zhang; Zuowei Xie

doi:10.1039/d4sc04980b

N=N bond cleavage in diazirines by a cyclic diborane(4) compound

Minling Zhong
, Jie Zhang
, Zuowei Xie^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

3 Citations (Scopus)

Abstract

Reactions of o-carborane-fused diborane(4) with 3H-diazirines led to the complete cleavage of the N=N bond, with one nitrogen atom being incorporated into the B–B bond. The molecular and electronic structures of the resultant borylnitrogen compounds were confirmed through single-crystal X-ray analyses and computational studies. The related reaction mechanism was investigated using DFT calculations.

Original language	English
Pages (from-to)	18048-18051
Number of pages	4
Journal	Chemical Science
Volume	15
Issue number	43
DOIs	https://doi.org/10.1039/d4sc04980b
Publication status	Published - 7 Oct 2024

Access to Document

10.1039/d4sc04980b

Cite this

@article{0df8bd2afd124bf88ad9119d95348d87,

title = "N=N bond cleavage in diazirines by a cyclic diborane(4) compound",

abstract = "Reactions of o-carborane-fused diborane(4) with 3H-diazirines led to the complete cleavage of the N=N bond, with one nitrogen atom being incorporated into the B–B bond. The molecular and electronic structures of the resultant borylnitrogen compounds were confirmed through single-crystal X-ray analyses and computational studies. The related reaction mechanism was investigated using DFT calculations.",

author = "Minling Zhong and Jie Zhang and Zuowei Xie",

note = "Funding information: This work was supported by grants from Shenzhen Science and Technology Program (Project No. QTD20221101093558015 to ZX), the National Natural Science Foundation of China (Project No. 22331005 to ZX) and Research Grants Council of HKSAR (Project No. 14307421 to ZJ). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2024",

year = "2024",

month = oct,

day = "7",

doi = "10.1039/d4sc04980b",

language = "English",

volume = "15",

pages = "18048--18051",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "43",

}

TY - JOUR

T1 - N=N bond cleavage in diazirines by a cyclic diborane(4) compound

AU - Zhong, Minling

AU - Zhang, Jie

AU - Xie, Zuowei

N1 - Funding information: This work was supported by grants from Shenzhen Science and Technology Program (Project No. QTD20221101093558015 to ZX), the National Natural Science Foundation of China (Project No. 22331005 to ZX) and Research Grants Council of HKSAR (Project No. 14307421 to ZJ). Publisher Copyright: © The Royal Society of Chemistry 2024

PY - 2024/10/7

Y1 - 2024/10/7

N2 - Reactions of o-carborane-fused diborane(4) with 3H-diazirines led to the complete cleavage of the N=N bond, with one nitrogen atom being incorporated into the B–B bond. The molecular and electronic structures of the resultant borylnitrogen compounds were confirmed through single-crystal X-ray analyses and computational studies. The related reaction mechanism was investigated using DFT calculations.

AB - Reactions of o-carborane-fused diborane(4) with 3H-diazirines led to the complete cleavage of the N=N bond, with one nitrogen atom being incorporated into the B–B bond. The molecular and electronic structures of the resultant borylnitrogen compounds were confirmed through single-crystal X-ray analyses and computational studies. The related reaction mechanism was investigated using DFT calculations.

UR - https://www.scopus.com/pages/publications/85206877365

U2 - 10.1039/d4sc04980b

DO - 10.1039/d4sc04980b

M3 - Journal article

AN - SCOPUS:85206877365

SN - 2041-6520

VL - 15

SP - 18048

EP - 18051

JO - Chemical Science

JF - Chemical Science

IS - 43

ER -

N=N bond cleavage in diazirines by a cyclic diborane(4) compound

Abstract

Access to Document

Other files and links

Fingerprint

Cite this