Nickel-catalyzed 1,2-dialkenylation of o-carboranes with alkenyl bromides

Qihang Zhuo; Jie Zhang; Zuowei Xie

doi:10.1039/d5dt02451j

Nickel-catalyzed 1,2-dialkenylation of o-carboranes with alkenyl bromides

Qihang Zhuo
, Jie Zhang^*
, Zuowei Xie^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

1 Citation (Scopus)

Abstract

A nickel-catalyzed cross-coupling reaction of o-carboranyl with alkenyl bromides has been developed, affording a series of 1,2-dialkenylated o-carboranes with a broad substrate scope. This reaction provides an efficient and concise strategy for C,C′-dialkenylation of o-carboranes and supplements the transition-metal catalyzed cage B–H functionalization systems.

Original language	English
Pages (from-to)	17430-17433
Number of pages	4
Journal	Dalton Transactions
Volume	54
Issue number	47
Early online date	6 Nov 2025
DOIs	https://doi.org/10.1039/d5dt02451j
Publication status	Published - 21 Dec 2025

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title = "Nickel-catalyzed 1,2-dialkenylation of o-carboranes with alkenyl bromides",

abstract = "A nickel-catalyzed cross-coupling reaction of o-carboranyl with alkenyl bromides has been developed, affording a series of 1,2-dialkenylated o-carboranes with a broad substrate scope. This reaction provides an efficient and concise strategy for C,C′-dialkenylation of o-carboranes and supplements the transition-metal catalyzed cage B–H functionalization systems.",

author = "Qihang Zhuo and Jie Zhang and Zuowei Xie",

note = "Funding information: This work was supported by grants from the Research Grants Council of the Hong Kong Special Administrative Region (Project No. 14305424 to J. Z.), the National Natural Science Foundation of China (Project No. 22331005 to Z. X. and 22201238 to J. Z.), and the Shenzhen Science and Technology Program (Project No. KQTD20221101093558015 to Z. X.). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2025",

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doi = "10.1039/d5dt02451j",

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T1 - Nickel-catalyzed 1,2-dialkenylation of o-carboranes with alkenyl bromides

AU - Zhuo, Qihang

AU - Zhang, Jie

AU - Xie, Zuowei

N1 - Funding information: This work was supported by grants from the Research Grants Council of the Hong Kong Special Administrative Region (Project No. 14305424 to J. Z.), the National Natural Science Foundation of China (Project No. 22331005 to Z. X. and 22201238 to J. Z.), and the Shenzhen Science and Technology Program (Project No. KQTD20221101093558015 to Z. X.). Publisher Copyright: © The Royal Society of Chemistry 2025

PY - 2025/12/21

Y1 - 2025/12/21

N2 - A nickel-catalyzed cross-coupling reaction of o-carboranyl with alkenyl bromides has been developed, affording a series of 1,2-dialkenylated o-carboranes with a broad substrate scope. This reaction provides an efficient and concise strategy for C,C′-dialkenylation of o-carboranes and supplements the transition-metal catalyzed cage B–H functionalization systems.

AB - A nickel-catalyzed cross-coupling reaction of o-carboranyl with alkenyl bromides has been developed, affording a series of 1,2-dialkenylated o-carboranes with a broad substrate scope. This reaction provides an efficient and concise strategy for C,C′-dialkenylation of o-carboranes and supplements the transition-metal catalyzed cage B–H functionalization systems.

UR - https://www.scopus.com/pages/publications/105022266301

U2 - 10.1039/d5dt02451j

DO - 10.1039/d5dt02451j

M3 - Journal article

C2 - 41268777

AN - SCOPUS:105022266301

SN - 1477-9226

VL - 54

SP - 17430

EP - 17433

JO - Dalton Transactions

JF - Dalton Transactions

IS - 47

ER -

Nickel-catalyzed 1,2-dialkenylation of o-carboranes with alkenyl bromides

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