Nickel-catalyzed 1,2-dialkenylation of o-carboranes with alkenyl bromides

  • Qihang Zhuo
  • , Jie Zhang*
  • , Zuowei Xie*
  • *Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

Abstract

A nickel-catalyzed cross-coupling reaction of o-carboranyl with alkenyl bromides has been developed, affording a series of 1,2-dialkenylated o-carboranes with a broad substrate scope. This reaction provides an efficient and concise strategy for C,C′-dialkenylation of o-carboranes and supplements the transition-metal catalyzed cage B–H functionalization systems.

Original languageEnglish
Pages (from-to)17430-17433
Number of pages4
JournalDalton Transactions
Volume54
Issue number47
Early online date6 Nov 2025
DOIs
Publication statusPublished - 21 Dec 2025

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