Abstract
A new kind of highly red emissive and transparent nanopapers as ultraviolet filter are produced from lanthanide complex Eu(TTA)3(H2O)2 grafted nanofibrillated cellulose (NFC) by a filtration process using a Buchner funnel. The nanopapers Eu-NFC 1–4 with different thickness (0.023 mm, 1; 0.04 mm, 2; 0.081 mm, 3 and 0.1 mm, 4) possess a fibres with dimensions of approximately 50 nm in diameter and several micrometres in length. Those nanopapers exhibit excellent ultraviolet A (UVA; 320–400 nm) filter property and high optical transmittance (>73% at wavelength of 600 nm). The presence of Eu(TTA)3(H2O)2 in Eu-NFC nanopapers can block 97% UVA (at 348 nm) light and convert it into pure red emission (CIE: x = 0.663, y = 0.333) through the efficient triplet-triplet energy transfer process. The efficient red emission can significantly improve the photo-stability of β-diketones type UVA filter. It can sustain for 10 h without decomposition under UV irradiation at 365 nm, which makes it possible to be applied in UVA filters. Moreover, its low coefficient of thermal expansion (CTE: 6.39 ppm K−1 of nanocellulose), is superior to petroleum-based materials for red organic light-emitting devices.
Original language | English |
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Pages (from-to) | 747-753 |
Number of pages | 7 |
Journal | Optical Materials |
Volume | 73 |
DOIs | |
Publication status | Published - Nov 2017 |
Scopus Subject Areas
- Electronic, Optical and Magnetic Materials
- General Computer Science
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Electrical and Electronic Engineering
User-Defined Keywords
- Lanthanide
- Photo-stability
- Pure red emission
- Transparent nanopapers
- β-diketones type UVA filter