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NAD+ capping of sibD transcripts in E. coli is mediated by its minimal promoter and enhanced by ppGpp

  • Wuzhen Liu
  • , Kefan Hu
  • , Shiqi Nie
  • , Feng Zhang
  • , Qiongfang Li
  • , Hailei Zhang
  • , Shumin Liang
  • , Jialin Peng
  • , Shoudong Zhang
  • , Zongwei Cai
  • , Yiji Xia*
  • *Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

Abstract

Recently, nicotinamide adenine dinucleotide (NAD+) and other nucleotide analogs have been identified as non-canonical RNA caps in both prokaryotes and eukaryotes. In Escherichia coli, NAD capping has been shown to be influenced by environmental conditions in a gene-specific manner, yet its regulatory mechanisms remain poorly understood. We previously reported that most transcripts produced by sibD are NAD-capped during the stationary phase. In this study, we found that the 35-bp minimal promoter of sibD is sufficient for its NAD capping. When this minimal promoter was applied to express genes not typically producing NAD-RNAs, their transcripts could also be NAD-capped. These findings strongly support that NAD capping in E. coli occurs during transcription initiation mediated by the promoter and RNA polymerase. Additionally, the bacterial alarmone ppGpp and the small protein DksA, both transcription initiation regulators, synergistically enhance transcription of both NAD-capped and uncapped RNAs from sibD and its homologous genes, sibC and sibE, in vitro. In contrast, the ppGpp⁰ mutant, deficient in ppGpp synthesis, showed a significant reduction in NAD-RNA production from these genes. Our findings elucidate the cis-elements and trans-acting factors mediating NAD capping during transcription initiation, offering novel insight into this regulatory process.
Original languageEnglish
Article numbergkag102
Number of pages19
JournalNucleic Acids Research
Volume54
Issue number5
DOIs
Publication statusPublished - 24 Feb 2026

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