Metallopolyyne polymers containing naphthalene diimide-oligothiophene moieties and their applications in organic field-effect transistors

Lei Yan; Chengxi Li; Lulu Cai; Keli Shi; Wei Tang; Wenxiu Qu; Cheuk Lam Ho; Gui Yu; Jiangyu Li; Xingzhu Wang

doi:10.1016/j.jorganchem.2017.05.027

Metallopolyyne polymers containing naphthalene diimide-oligothiophene moieties and their applications in organic field-effect transistors

Lei Yan
, Chengxi Li
, Lulu Cai
, Keli Shi
, Wei Tang
, Wenxiu Qu
, Cheuk Lam Ho
, Gui Yu
, Jiangyu Li
, Xingzhu Wang^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

10 Citations (Scopus)

Abstract

Two novel platinum(II) donor-acceptor (D-A) naphthalene diimide (NDI)-based copolymers have been designed and synthesized. The effects of thiophene numbers on the thermal, optical, electronic and charge transport properties of the polymers have been investigated. These solution processable polymers exhibit p-channel field-effect charge transport characteristics, unlike other organic NDI-based polymeric analogues. All the results indicated that they have potential applications in high-performance organic field-effect transistors (OFETs).

Original language	English
Pages (from-to)	269-276
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	846
DOIs	https://doi.org/10.1016/j.jorganchem.2017.05.027
Publication status	Published - 1 Oct 2017

User-Defined Keywords

Metallopolyynes
Naphthalene diimide (NDI)
Oligothiophene
Organic field-effect transistors (OFETs)
Platinum

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10.1016/j.jorganchem.2017.05.027

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@article{baecf4d38f024ea6b62cf3efd9e0ac58,

title = "Metallopolyyne polymers containing naphthalene diimide-oligothiophene moieties and their applications in organic field-effect transistors",

abstract = "Two novel platinum(II) donor-acceptor (D-A) naphthalene diimide (NDI)-based copolymers have been designed and synthesized. The effects of thiophene numbers on the thermal, optical, electronic and charge transport properties of the polymers have been investigated. These solution processable polymers exhibit p-channel field-effect charge transport characteristics, unlike other organic NDI-based polymeric analogues. All the results indicated that they have potential applications in high-performance organic field-effect transistors (OFETs).",

keywords = "Metallopolyynes, Naphthalene diimide (NDI), Oligothiophene, Organic field-effect transistors (OFETs), Platinum",

author = "Lei Yan and Chengxi Li and Lulu Cai and Keli Shi and Wei Tang and Wenxiu Qu and Ho, \{Cheuk Lam\} and Gui Yu and Jiangyu Li and Xingzhu Wang",

note = "Funding Information: This work was financially supported by the National Nature Science Foundation of China (Nos. 51473053, 20974091, 50803051 and 91333206), the project of Innovation Platform Open Foundation of University of Hunan Province (14K092) and Hunan 2011 Collaborative Innovation Center of Chemical Engineering \& Technology with Environmental Benignity and Effective Resource Utilization for the financial support. W. Qu thanks the Xiangtan University Undergraduate Innovative Experiment Program. C.-L. Ho thanks Hong Kong Baptist University (FRG1/15-16/043 and FRG2/15-16/074), the Science, Technology and Innovation Committee of Shenzhen Municipality (JCYJ20140818163041143) and the National Natural Science Foundation of China (project number 21504074) for their financial support. The present work was also supported by the Inter-institutional Collaborative Research Scheme, Hong Kong Baptist University and Hong Kong Polytechnic University (RC-ICRS/14-15/02).",

year = "2017",

month = oct,

day = "1",

doi = "10.1016/j.jorganchem.2017.05.027",

language = "English",

volume = "846",

pages = "269--276",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Metallopolyyne polymers containing naphthalene diimide-oligothiophene moieties and their applications in organic field-effect transistors

AU - Yan, Lei

AU - Li, Chengxi

AU - Cai, Lulu

AU - Shi, Keli

AU - Tang, Wei

AU - Qu, Wenxiu

AU - Ho, Cheuk Lam

AU - Yu, Gui

AU - Li, Jiangyu

AU - Wang, Xingzhu

N1 - Funding Information: This work was financially supported by the National Nature Science Foundation of China (Nos. 51473053, 20974091, 50803051 and 91333206), the project of Innovation Platform Open Foundation of University of Hunan Province (14K092) and Hunan 2011 Collaborative Innovation Center of Chemical Engineering & Technology with Environmental Benignity and Effective Resource Utilization for the financial support. W. Qu thanks the Xiangtan University Undergraduate Innovative Experiment Program. C.-L. Ho thanks Hong Kong Baptist University (FRG1/15-16/043 and FRG2/15-16/074), the Science, Technology and Innovation Committee of Shenzhen Municipality (JCYJ20140818163041143) and the National Natural Science Foundation of China (project number 21504074) for their financial support. The present work was also supported by the Inter-institutional Collaborative Research Scheme, Hong Kong Baptist University and Hong Kong Polytechnic University (RC-ICRS/14-15/02).

PY - 2017/10/1

Y1 - 2017/10/1

N2 - Two novel platinum(II) donor-acceptor (D-A) naphthalene diimide (NDI)-based copolymers have been designed and synthesized. The effects of thiophene numbers on the thermal, optical, electronic and charge transport properties of the polymers have been investigated. These solution processable polymers exhibit p-channel field-effect charge transport characteristics, unlike other organic NDI-based polymeric analogues. All the results indicated that they have potential applications in high-performance organic field-effect transistors (OFETs).

AB - Two novel platinum(II) donor-acceptor (D-A) naphthalene diimide (NDI)-based copolymers have been designed and synthesized. The effects of thiophene numbers on the thermal, optical, electronic and charge transport properties of the polymers have been investigated. These solution processable polymers exhibit p-channel field-effect charge transport characteristics, unlike other organic NDI-based polymeric analogues. All the results indicated that they have potential applications in high-performance organic field-effect transistors (OFETs).

KW - Metallopolyynes

KW - Naphthalene diimide (NDI)

KW - Oligothiophene

KW - Organic field-effect transistors (OFETs)

KW - Platinum

UR - https://www.scopus.com/pages/publications/85021775501

U2 - 10.1016/j.jorganchem.2017.05.027

DO - 10.1016/j.jorganchem.2017.05.027

M3 - Journal article

AN - SCOPUS:85021775501

SN - 0022-328X

VL - 846

SP - 269

EP - 276

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Metallopolyyne polymers containing naphthalene diimide-oligothiophene moieties and their applications in organic field-effect transistors

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