Metal-indolizine zwitterion complexes as a new class of organometallic material: A spectroscopic and theoretical investigation

Lai Hon Chung, Chi Fung Yeung, Edmond Dik Lung MA, Chung Hang Leung, Chun Yuen Wong*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

27 Citations (Scopus)

Abstract

Indolizine zwitterion coordinated metal species have been commonly proposed as intermediates in the mechanisms of metal-catalyzed cycloisomerization of propargylic pyridines for indolizines. Yet, it is only recently that the first metal-indolizine complexes have been isolated by our group. Considering from the perspective of molecular materials, the π-interaction between the d π(M) and the π-system of the indolizine skeleton in the electronic ground or excited states may allow charge delocalization and offer functionalities for optoelectronic applications. We herein report the synthesis and spectroscopic and theoretical investigations on two classes of Ru-indolizine zwitterion complexes. The synthetic strategy employed, i.e., cycloisomerization of propargylic pyridines, represents a general preparation method for stable metal-indolizine complexes. Indolizine zwitterions in this work have been found to exhibit strong trans effect. Spectroscopic studies on these complexes reveals the tunability of the π*(indolizine) level and its impact on the luminophores nearby. Overall, indolizine zwitterion represents a new class of organometallic ligand with high potential in the design of functional molecular electronic/photonic elements.

Original languageEnglish
Pages (from-to)3443-3452
Number of pages10
JournalOrganometallics
Volume33
Issue number13
DOIs
Publication statusPublished - 14 Jul 2014

Scopus Subject Areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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