@inbook{95104b0594824576b558fdfc72989627,
title = "Mechanistic Studies of Rhodium-Catalyzed Asymmetric Homogeneous Hydrogenation",
abstract = "The reaction pathway for rhodium-catalyzed asymmetric hydrogenation of enamides is described and intermediates are defined in solution by P-31, C-13, and H-1 NMR. The stereochemical relationship of bound enamide to rhodium alkyl and to the product of hydrogenation is demonstrated. Experiments involving the addition of HD to a variety of olefins in the presence of rhodium biphosphine catalysts suggest that a concerted addition of hydrogen to olefin and metal may occur in appropriate cases.",
author = "Brown, \{John M.\} and Chaloner, \{Penny A.\} and David Parker",
year = "1982",
month = jun,
day = "1",
doi = "10.1021/ba-1982-0196.ch022",
language = "English",
isbn = "9780841206014",
series = "Advances in Chemistry",
publisher = "American Chemical Society",
pages = "355--369",
editor = "Alyea, \{Elmer C.\} and Meek, \{Devon W.\}",
booktitle = "Catalytic Aspects of Metal Phosphine Complexes",
address = "United States",
}