Mechanism of epimerization of 2,3‐erythro‐aldoses to 2,3‐threo‐Aldoses: An NMR study

Albert W M Lee

doi:10.1002/mrc.1260230612

Mechanism of epimerization of 2,3‐erythro‐aldoses to 2,3‐threo‐Aldoses: An NMR study

Albert W M Lee^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

12 Citations (Scopus)

Abstract

Proton NMR spectroscopic studies on the conversion of 2,3‐erythro‐aldoses to 2,3‐threo‐aldoses in methanolic K₂CO₃ solution revealed the formation of the hemiacetals of the corresponding aldehydes, which probably provided the driving force of the easy epimerization.

Original language	English
Pages (from-to)	468-469
Number of pages	2
Journal	Magnetic Resonance in Chemistry
Volume	23
Issue number	6
DOIs	https://doi.org/10.1002/mrc.1260230612
Publication status	Published - Jun 1985

Scopus Subject Areas

General Chemistry
General Materials Science

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title = "Mechanism of epimerization of 2,3‐erythro‐aldoses to 2,3‐threo‐Aldoses: An NMR study",

abstract = "Proton NMR spectroscopic studies on the conversion of 2,3‐erythro‐aldoses to 2,3‐threo‐aldoses in methanolic K2CO3 solution revealed the formation of the hemiacetals of the corresponding aldehydes, which probably provided the driving force of the easy epimerization.",

author = "Lee, {Albert W M}",

year = "1985",

month = jun,

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journal = "Magnetic Resonance in Chemistry",

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T1 - Mechanism of epimerization of 2,3‐erythro‐aldoses to 2,3‐threo‐Aldoses

T2 - An NMR study

AU - Lee, Albert W M

PY - 1985/6

Y1 - 1985/6

N2 - Proton NMR spectroscopic studies on the conversion of 2,3‐erythro‐aldoses to 2,3‐threo‐aldoses in methanolic K2CO3 solution revealed the formation of the hemiacetals of the corresponding aldehydes, which probably provided the driving force of the easy epimerization.

AB - Proton NMR spectroscopic studies on the conversion of 2,3‐erythro‐aldoses to 2,3‐threo‐aldoses in methanolic K2CO3 solution revealed the formation of the hemiacetals of the corresponding aldehydes, which probably provided the driving force of the easy epimerization.

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U2 - 10.1002/mrc.1260230612

DO - 10.1002/mrc.1260230612

M3 - Journal article

AN - SCOPUS:84986812438

SN - 0749-1581

VL - 23

SP - 468

EP - 469

JO - Magnetic Resonance in Chemistry

JF - Magnetic Resonance in Chemistry

IS - 6

ER -

Mechanism of epimerization of 2,3‐erythro‐aldoses to 2,3‐threo‐Aldoses: An NMR study

Abstract

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