Macrocyclic-ligand Induced Synthesis of Aryl Ethynides with Divergent Silver(I) Clusters

Guangmian Ji; Siqi Zhang; Sam C.K. Hau; Liang Zhao

doi:10.1002/cjoc.201700481

Macrocyclic-ligand Induced Synthesis of Aryl Ethynides with Divergent Silver(I) Clusters

Guangmian Ji, Siqi Zhang, Sam C.K. Hau, Liang Zhao^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

7 Citations (Scopus)

Abstract

Two structurally characterized metal-cluster-centered supramolecular architectures named [Ag₈(1,2-(C ≡ C)₂-C₆H₄)(Py[6])(CF₃CO₂)₆] · 2.5MeOH (1) and [Ag₁₂(1,2,4,5-(C ≡ C)₄C₆H₂)(Py[6])₂(CF₃SO₃)₈]·4MeOH·3H₂O (2) are synthesized through the interaction with a bowl-shaped macrocyclic ligand Py[6]. Particularly, two dissimilar silver(I) clusters are resulted in 2 within the structure under the influence of the macrocyclic ligand Py[6]. Such dissimilarity of the silver(I) cluster is also reflected on the structural and photophysical differences between 1 and 2.

Original language	English
Pages (from-to)	1824-1828
Number of pages	5
Journal	Chinese Journal of Chemistry
Volume	35
Issue number	12
DOIs	https://doi.org/10.1002/cjoc.201700481
Publication status	Published - 1 Dec 2017

Scopus Subject Areas

General Chemistry

User-Defined Keywords

Dissimilarity
Macrocycle
Silver Clusters
Silver Ethynide
Supramolecular Architecture

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10.1002/cjoc.201700481

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@article{4cef2b718b5e4cf781bce02c7d3f0bbb,

title = "Macrocyclic-ligand Induced Synthesis of Aryl Ethynides with Divergent Silver(I) Clusters",

abstract = "Two structurally characterized metal-cluster-centered supramolecular architectures named [Ag8(1,2-(C ≡ C)2-C6H4)(Py[6])(CF3CO2)6] · 2.5MeOH (1) and [Ag12(1,2,4,5-(C ≡ C)4C6H2)(Py[6])2(CF3SO3)8]·4MeOH·3H2O (2) are synthesized through the interaction with a bowl-shaped macrocyclic ligand Py[6]. Particularly, two dissimilar silver(I) clusters are resulted in 2 within the structure under the influence of the macrocyclic ligand Py[6]. Such dissimilarity of the silver(I) cluster is also reflected on the structural and photophysical differences between 1 and 2.",

keywords = "Dissimilarity, Macrocycle, Silver Clusters, Silver Ethynide, Supramolecular Architecture",

author = "Guangmian Ji and Siqi Zhang and Hau, {Sam C.K.} and Liang Zhao",

note = "Funding Information: Financial support by NNSFC (21522206 and 21421064), MOST (2013CB834501) and Tsinghua University (C2017165) is gratefully acknowledged.",

year = "2017",

month = dec,

day = "1",

doi = "10.1002/cjoc.201700481",

language = "English",

volume = "35",

pages = "1824--1828",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "Wiley-Blackwell",

number = "12",

}

TY - JOUR

T1 - Macrocyclic-ligand Induced Synthesis of Aryl Ethynides with Divergent Silver(I) Clusters

AU - Ji, Guangmian

AU - Zhang, Siqi

AU - Hau, Sam C.K.

AU - Zhao, Liang

N1 - Funding Information: Financial support by NNSFC (21522206 and 21421064), MOST (2013CB834501) and Tsinghua University (C2017165) is gratefully acknowledged.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - Two structurally characterized metal-cluster-centered supramolecular architectures named [Ag8(1,2-(C ≡ C)2-C6H4)(Py[6])(CF3CO2)6] · 2.5MeOH (1) and [Ag12(1,2,4,5-(C ≡ C)4C6H2)(Py[6])2(CF3SO3)8]·4MeOH·3H2O (2) are synthesized through the interaction with a bowl-shaped macrocyclic ligand Py[6]. Particularly, two dissimilar silver(I) clusters are resulted in 2 within the structure under the influence of the macrocyclic ligand Py[6]. Such dissimilarity of the silver(I) cluster is also reflected on the structural and photophysical differences between 1 and 2.

AB - Two structurally characterized metal-cluster-centered supramolecular architectures named [Ag8(1,2-(C ≡ C)2-C6H4)(Py[6])(CF3CO2)6] · 2.5MeOH (1) and [Ag12(1,2,4,5-(C ≡ C)4C6H2)(Py[6])2(CF3SO3)8]·4MeOH·3H2O (2) are synthesized through the interaction with a bowl-shaped macrocyclic ligand Py[6]. Particularly, two dissimilar silver(I) clusters are resulted in 2 within the structure under the influence of the macrocyclic ligand Py[6]. Such dissimilarity of the silver(I) cluster is also reflected on the structural and photophysical differences between 1 and 2.

KW - Dissimilarity

KW - Macrocycle

KW - Silver Clusters

KW - Silver Ethynide

KW - Supramolecular Architecture

UR - http://www.scopus.com/inward/record.url?scp=85037329346&partnerID=8YFLogxK

U2 - 10.1002/cjoc.201700481

DO - 10.1002/cjoc.201700481

M3 - Journal article

AN - SCOPUS:85037329346

SN - 1001-604X

VL - 35

SP - 1824

EP - 1828

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 12

ER -

Macrocyclic-ligand Induced Synthesis of Aryl Ethynides with Divergent Silver(I) Clusters

Abstract

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