Macrocyclic-ligand Induced Synthesis of Aryl Ethynides with Divergent Silver(I) Clusters

Guangmian Ji, Siqi Zhang, Sam C K HAU, Liang Zhao*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Two structurally characterized metal-cluster-centered supramolecular architectures named [Ag8(1,2-(C ≡ C)2-C6H4)(Py[6])(CF3CO2)6] · 2.5MeOH (1) and [Ag12(1,2,4,5-(C ≡ C)4C6H2)(Py[6])2(CF3SO3)8]·4MeOH·3H2O (2) are synthesized through the interaction with a bowl-shaped macrocyclic ligand Py[6]. Particularly, two dissimilar silver(I) clusters are resulted in 2 within the structure under the influence of the macrocyclic ligand Py[6]. Such dissimilarity of the silver(I) cluster is also reflected on the structural and photophysical differences between 1 and 2.

Original languageEnglish
Pages (from-to)1824-1828
Number of pages5
JournalChinese Journal of Chemistry
Volume35
Issue number12
DOIs
Publication statusPublished - 1 Dec 2017

Scopus Subject Areas

  • Chemistry(all)

User-Defined Keywords

  • Dissimilarity
  • Macrocycle
  • Silver Clusters
  • Silver Ethynide
  • Supramolecular Architecture

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