TY - JOUR
T1 - Layer-by-layer self-assembled vanadium dioxide and its temperature-dependent light interference
AU - Hu, Hebing
AU - Meng, Yun
AU - Wang, Jiarui
AU - Wang, Shancheng
AU - Vu, Tuan Duc
AU - Long, Yi
N1 - The Principal Investigator of this project (Y.L.) wishes to thank Sino-Singapore International Joint Research Institute for funding support. This research is supported by the Singapore Ministry of Education (MOE) Academic Research Fund Tier One RG200/17, RG103/19 and the National Research Foundation, Prime Minister’s Office, Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) programme.
Publisher Copyright:
© 2021
PY - 2022/3/1
Y1 - 2022/3/1
N2 - Vanadium Dioxide (VO2) has gained wide attention for various applications as it undergoes a crystallographic transition from the monoclinic phase to the tetragonal phase at 68 °C, accompanied by huge transmittance contrast in the near-infrared (NIR) range and negligible change in the visible range. In this paper, we present a unique Layer-by-Layer self-assembled approach to construct a VO2/spacing superstructure with controlled VO2 layers, spacing thicknesses, and repeating times. The simulation indicates that such structures give intriguingly temperature-dependent light interference phenomena, which was demonstrated its potential applications in smart windows and the calculated results suggest this approach outperforms existing approaches. This simple and versatile solution-based approach opens a new avenue to fabricate the controlled optical stack which could be explored in other applications.
AB - Vanadium Dioxide (VO2) has gained wide attention for various applications as it undergoes a crystallographic transition from the monoclinic phase to the tetragonal phase at 68 °C, accompanied by huge transmittance contrast in the near-infrared (NIR) range and negligible change in the visible range. In this paper, we present a unique Layer-by-Layer self-assembled approach to construct a VO2/spacing superstructure with controlled VO2 layers, spacing thicknesses, and repeating times. The simulation indicates that such structures give intriguingly temperature-dependent light interference phenomena, which was demonstrated its potential applications in smart windows and the calculated results suggest this approach outperforms existing approaches. This simple and versatile solution-based approach opens a new avenue to fabricate the controlled optical stack which could be explored in other applications.
KW - Energy-saving smart windows
KW - Layer-by-layer assembly
KW - Superstructure
KW - Temperature-dependent interference
KW - Vanadium dioxide
UR - http://www.scopus.com/inward/record.url?scp=85120744471&partnerID=8YFLogxK
UR - https://www.sciencedirect.com/science/article/pii/S1385894721055510?via%3Dihub
U2 - 10.1016/j.cej.2021.133978
DO - 10.1016/j.cej.2021.133978
M3 - Journal article
AN - SCOPUS:85120744471
SN - 1385-8947
VL - 431
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
M1 - 133978
ER -