Investigation of deuterium isotope effects in the carbon dioxide reforming of methane to syngas over rhodium catalysts

Hai You Wang; Chak Tong Au

Investigation of deuterium isotope effects in the carbon dioxide reforming of methane to syngas over rhodium catalysts

Hai You Wang^*
, Chak Tong Au

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

Abstract

Deuterium isotope effects in the CO₂-reforming of methane to syngas were first investigated over SiO₂-supported rhodium catalysts. Normal deuterium isotope effect was more noticeable on the methane conversion reaction than on the CO formation reaction, while there was no such effect on the CO₂ conversion reaction. It can be concluded that the dissociation of the C-H bond in methane is a key step and some CO is formed by the reverse water-gas shift reaction.

Original language	English
Pages (from-to)	1047-1050
Number of pages	4
Journal	Chinese Chemical Letters
Volume	7
Issue number	11
Publication status	Published - 1996

Cite this

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title = "Investigation of deuterium isotope effects in the carbon dioxide reforming of methane to syngas over rhodium catalysts",

abstract = "Deuterium isotope effects in the CO2-reforming of methane to syngas were first investigated over SiO2-supported rhodium catalysts. Normal deuterium isotope effect was more noticeable on the methane conversion reaction than on the CO formation reaction, while there was no such effect on the CO2 conversion reaction. It can be concluded that the dissociation of the C-H bond in methane is a key step and some CO is formed by the reverse water-gas shift reaction.",

author = "Wang, \{Hai You\} and Au, \{Chak Tong\}",

year = "1996",

language = "English",

volume = "7",

pages = "1047--1050",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "11",

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TY - JOUR

T1 - Investigation of deuterium isotope effects in the carbon dioxide reforming of methane to syngas over rhodium catalysts

AU - Wang, Hai You

AU - Au, Chak Tong

PY - 1996

Y1 - 1996

N2 - Deuterium isotope effects in the CO2-reforming of methane to syngas were first investigated over SiO2-supported rhodium catalysts. Normal deuterium isotope effect was more noticeable on the methane conversion reaction than on the CO formation reaction, while there was no such effect on the CO2 conversion reaction. It can be concluded that the dissociation of the C-H bond in methane is a key step and some CO is formed by the reverse water-gas shift reaction.

AB - Deuterium isotope effects in the CO2-reforming of methane to syngas were first investigated over SiO2-supported rhodium catalysts. Normal deuterium isotope effect was more noticeable on the methane conversion reaction than on the CO formation reaction, while there was no such effect on the CO2 conversion reaction. It can be concluded that the dissociation of the C-H bond in methane is a key step and some CO is formed by the reverse water-gas shift reaction.

UR - https://www.scopus.com/pages/publications/0030515897

M3 - Journal article

AN - SCOPUS:0030515897

SN - 1001-8417

VL - 7

SP - 1047

EP - 1050

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 11

ER -

Investigation of deuterium isotope effects in the carbon dioxide reforming of methane to syngas over rhodium catalysts

Abstract

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