Interaction of alkyl halides with the di-ironoctacarbonylate anion: The crystal structures of the tetraethylammonium salts of the μ-acetyl-C1(Fe1, Fe2)O(Fe1, Fe3)-nonacarbonyl-triangulo-triferrate and μ2-carbonylnonacabonyl-μ3-2,4-dioxapentylidyne-triangulo-triferrate anions

Wai Kwok Wong; Geoffrey Wilkinson; Anita M.R. Galas; Michael B. Hursthouse; Mark Thornton-Pett

doi:10.1039/C39810000189

Interaction of alkyl halides with the di-ironoctacarbonylate anion: The crystal structures of the tetraethylammonium salts of the μ-acetyl-C¹(Fe¹, Fe²)O(Fe¹, Fe³)-nonacarbonyl-triangulo-triferrate and μ₂-carbonylnonacabonyl-μ₃-2,4-dioxapentylidyne-triangulo-triferrate anions

Wai Kwok Wong^*
, Geoffrey Wilkinson
, Anita M.R. Galas
, Michael B. Hursthouse
, Mark Thornton-Pett

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

5 Citations (Scopus)

Abstract

The di-iron carbonylate anion [Fe₂(CO)₈]^2- reacts with methyl iodide and with chloromethyl methyl ether to give, respectively, the tri-iron cluster anions [Fe₃(CO) ₉(μ-MeCO)]^- and [Fe₃(CO)₉(μ- CO)(μ³-COCH_2-OMe)]^-, the former having a new type of bridging acetyl group.

Original language	English
Pages (from-to)	189-191
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39810000189
Publication status	Published - Feb 1981

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Wong, W. K., Wilkinson, G., Galas, A. M. R., Hursthouse, M. B., & Thornton-Pett, M. (1981). Interaction of alkyl halides with the di-ironoctacarbonylate anion: The crystal structures of the tetraethylammonium salts of the μ-acetyl-C¹(Fe¹, Fe²)O(Fe¹, Fe³)-nonacarbonyl-triangulo-triferrate and μ₂-carbonylnonacabonyl-μ₃-2,4-dioxapentylidyne-triangulo-triferrate anions. Journal of the Chemical Society, Chemical Communications, (4), 189-191. https://doi.org/10.1039/C39810000189

Wong, Wai Kwok ; Wilkinson, Geoffrey ; Galas, Anita M.R. et al. / Interaction of alkyl halides with the di-ironoctacarbonylate anion : The crystal structures of the tetraethylammonium salts of the μ-acetyl-C¹(Fe¹, Fe²)O(Fe¹, Fe³)-nonacarbonyl-triangulo-triferrate and μ₂-carbonylnonacabonyl-μ₃-2,4-dioxapentylidyne-triangulo-triferrate anions. In: Journal of the Chemical Society, Chemical Communications. 1981 ; No. 4. pp. 189-191.

@article{ea76c53ac06544dd963321ae53dfc6e7,

title = "Interaction of alkyl halides with the di-ironoctacarbonylate anion: The crystal structures of the tetraethylammonium salts of the μ-acetyl-C1(Fe1, Fe2)O(Fe1, Fe3)-nonacarbonyl-triangulo-triferrate and μ2-carbonylnonacabonyl-μ3-2,4-dioxapentylidyne-triangulo-triferrate anions",

abstract = "The di-iron carbonylate anion [Fe2(CO)8]2- reacts with methyl iodide and with chloromethyl methyl ether to give, respectively, the tri-iron cluster anions [Fe3(CO) 9(μ-MeCO)]- and [Fe3(CO)9(μ- CO)(μ3-COCH2-OMe)]-, the former having a new type of bridging acetyl group.",

author = "Wong, \{Wai Kwok\} and Geoffrey Wilkinson and Galas, \{Anita M.R.\} and Hursthouse, \{Michael B.\} and Mark Thornton-Pett",

year = "1981",

month = feb,

doi = "10.1039/C39810000189",

language = "English",

pages = "189--191",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "4",

}

Wong, WK, Wilkinson, G, Galas, AMR, Hursthouse, MB & Thornton-Pett, M 1981, 'Interaction of alkyl halides with the di-ironoctacarbonylate anion: The crystal structures of the tetraethylammonium salts of the μ-acetyl-C¹(Fe¹, Fe²)O(Fe¹, Fe³)-nonacarbonyl-triangulo-triferrate and μ₂-carbonylnonacabonyl-μ₃-2,4-dioxapentylidyne-triangulo-triferrate anions', Journal of the Chemical Society, Chemical Communications, no. 4, pp. 189-191. https://doi.org/10.1039/C39810000189

Interaction of alkyl halides with the di-ironoctacarbonylate anion: The crystal structures of the tetraethylammonium salts of the μ-acetyl-C¹(Fe¹, Fe²)O(Fe¹, Fe³)-nonacarbonyl-triangulo-triferrate and μ₂-carbonylnonacabonyl-μ₃-2,4-dioxapentylidyne-triangulo-triferrate anions. / Wong, Wai Kwok; Wilkinson, Geoffrey; Galas, Anita M.R. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 4, 02.1981, p. 189-191.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Interaction of alkyl halides with the di-ironoctacarbonylate anion

T2 - The crystal structures of the tetraethylammonium salts of the μ-acetyl-C1(Fe1, Fe2)O(Fe1, Fe3)-nonacarbonyl-triangulo-triferrate and μ2-carbonylnonacabonyl-μ3-2,4-dioxapentylidyne-triangulo-triferrate anions

AU - Wong, Wai Kwok

AU - Wilkinson, Geoffrey

AU - Galas, Anita M.R.

AU - Hursthouse, Michael B.

AU - Thornton-Pett, Mark

PY - 1981/2

Y1 - 1981/2

N2 - The di-iron carbonylate anion [Fe2(CO)8]2- reacts with methyl iodide and with chloromethyl methyl ether to give, respectively, the tri-iron cluster anions [Fe3(CO) 9(μ-MeCO)]- and [Fe3(CO)9(μ- CO)(μ3-COCH2-OMe)]-, the former having a new type of bridging acetyl group.

AB - The di-iron carbonylate anion [Fe2(CO)8]2- reacts with methyl iodide and with chloromethyl methyl ether to give, respectively, the tri-iron cluster anions [Fe3(CO) 9(μ-MeCO)]- and [Fe3(CO)9(μ- CO)(μ3-COCH2-OMe)]-, the former having a new type of bridging acetyl group.

UR - https://www.scopus.com/pages/publications/37049113226

U2 - 10.1039/C39810000189

DO - 10.1039/C39810000189

M3 - Journal article

AN - SCOPUS:37049113226

SN - 0022-4936

SP - 189

EP - 191

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 4

ER -