Influence of nanoscale morphology on performance of inverted structure metallated conjugated polymer solar cells

Lal Mohammad; Abu Mitul; Qi Wang; Swaminathan Venkatesan; Devendra Khatiwada; Ashish Dubey; Cheuk Lam HO; Wai Yeung WONG; Qiquan Qiao

doi:10.1109/TED.2015.2455060

Influence of nanoscale morphology on performance of inverted structure metallated conjugated polymer solar cells

Lal Mohammad, Abu Mitul, Qi Wang, Swaminathan Venkatesan, Devendra Khatiwada, Ashish Dubey, Cheuk Lam HO, Wai Yeung WONG^*, Qiquan Qiao

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Inverted polymer solar cells (iPSCs) have shown a great potential in organic photovoltaics due to its enhanced stability and large-scale roll-to-roll processing. Metallated conjugated polymers also show promise as a donor material in the PSCs. In this paper, the role of solvents on the performance of inverted structure metallated PSCs was understood. Chlorobenzene (CB) and toluene were used as solvents to obtain the optimum morphology for improved device efficiency. To understand the charge transport properties and charge carrier lifetime in metallated polymer iPSCs, atomic force microscopy and transient photocurrent measurements were performed. The results showed that the CB as a solvent can improve the morphology of the active layer and enhance the performance of metallated iPSCs.

Original language	English
Article number	7173016
Pages (from-to)	3029-3033
Number of pages	5
Journal	IEEE Transactions on Electron Devices
Volume	62
Issue number	9
DOIs	https://doi.org/10.1109/TED.2015.2455060
Publication status	Published - 1 Sep 2015

Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Electrical and Electronic Engineering

User-Defined Keywords

Inverted structure
metallated conjugated polymers
nanoscale morphology
polymer solar cells (PSCs).

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10.1109/TED.2015.2455060

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title = "Influence of nanoscale morphology on performance of inverted structure metallated conjugated polymer solar cells",

abstract = "Inverted polymer solar cells (iPSCs) have shown a great potential in organic photovoltaics due to its enhanced stability and large-scale roll-to-roll processing. Metallated conjugated polymers also show promise as a donor material in the PSCs. In this paper, the role of solvents on the performance of inverted structure metallated PSCs was understood. Chlorobenzene (CB) and toluene were used as solvents to obtain the optimum morphology for improved device efficiency. To understand the charge transport properties and charge carrier lifetime in metallated polymer iPSCs, atomic force microscopy and transient photocurrent measurements were performed. The results showed that the CB as a solvent can improve the morphology of the active layer and enhance the performance of metallated iPSCs.",

keywords = "Inverted structure, metallated conjugated polymers, nanoscale morphology, polymer solar cells (PSCs).",

author = "Lal Mohammad and Abu Mitul and Qi Wang and Swaminathan Venkatesan and Devendra Khatiwada and Ashish Dubey and HO, {Cheuk Lam} and WONG, {Wai Yeung} and Qiquan Qiao",

year = "2015",

month = sep,

day = "1",

doi = "10.1109/TED.2015.2455060",

language = "English",

volume = "62",

pages = "3029--3033",

journal = "IEEE Transactions on Electron Devices",

issn = "0018-9383",

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Influence of nanoscale morphology on performance of inverted structure metallated conjugated polymer solar cells. / Mohammad, Lal; Mitul, Abu; Wang, Qi; Venkatesan, Swaminathan; Khatiwada, Devendra; Dubey, Ashish; HO, Cheuk Lam; WONG, Wai Yeung; Qiao, Qiquan.

In: IEEE Transactions on Electron Devices, Vol. 62, No. 9, 7173016, 01.09.2015, p. 3029-3033.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Influence of nanoscale morphology on performance of inverted structure metallated conjugated polymer solar cells

AU - Mohammad, Lal

AU - Mitul, Abu

AU - Wang, Qi

AU - Venkatesan, Swaminathan

AU - Khatiwada, Devendra

AU - Dubey, Ashish

AU - HO, Cheuk Lam

AU - WONG, Wai Yeung

AU - Qiao, Qiquan

PY - 2015/9/1

Y1 - 2015/9/1

N2 - Inverted polymer solar cells (iPSCs) have shown a great potential in organic photovoltaics due to its enhanced stability and large-scale roll-to-roll processing. Metallated conjugated polymers also show promise as a donor material in the PSCs. In this paper, the role of solvents on the performance of inverted structure metallated PSCs was understood. Chlorobenzene (CB) and toluene were used as solvents to obtain the optimum morphology for improved device efficiency. To understand the charge transport properties and charge carrier lifetime in metallated polymer iPSCs, atomic force microscopy and transient photocurrent measurements were performed. The results showed that the CB as a solvent can improve the morphology of the active layer and enhance the performance of metallated iPSCs.

AB - Inverted polymer solar cells (iPSCs) have shown a great potential in organic photovoltaics due to its enhanced stability and large-scale roll-to-roll processing. Metallated conjugated polymers also show promise as a donor material in the PSCs. In this paper, the role of solvents on the performance of inverted structure metallated PSCs was understood. Chlorobenzene (CB) and toluene were used as solvents to obtain the optimum morphology for improved device efficiency. To understand the charge transport properties and charge carrier lifetime in metallated polymer iPSCs, atomic force microscopy and transient photocurrent measurements were performed. The results showed that the CB as a solvent can improve the morphology of the active layer and enhance the performance of metallated iPSCs.

KW - Inverted structure

KW - metallated conjugated polymers

KW - nanoscale morphology

KW - polymer solar cells (PSCs).

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U2 - 10.1109/TED.2015.2455060

DO - 10.1109/TED.2015.2455060

M3 - Article

AN - SCOPUS:85028223543

VL - 62

SP - 3029

EP - 3033

JO - IEEE Transactions on Electron Devices

JF - IEEE Transactions on Electron Devices

SN - 0018-9383

IS - 9

M1 - 7173016

ER -

Influence of nanoscale morphology on performance of inverted structure metallated conjugated polymer solar cells

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