TY - JOUR
T1 - Improved properties of keratin-based bioplastic film blended with microcrystalline cellulose
T2 - A comparative analysis
AU - Alashwal, Basma Y.
AU - Saad Bala, Mohamed
AU - Gupta, Arun
AU - Sharma, Swati
AU - Mishra, Puranjan
N1 - Publisher Copyright:
© 2019
PY - 2020/1
Y1 - 2020/1
N2 - In the present study, bioplastic films were developed using the different ratio of keratin extracted from chicken feathers and cellulose. Firstly, bioplastic (K-60) was developed from the keratin, extracted from the chicken feathers using an alkaline agent (NaOH), and mixed with PVA/glycerol to synthesize protein-based bioplastic. Further, microcrystalline cellulose (2%) was used as an additive to K-60 bioplastic to develop an improved bioplastic (KC-60). The results of functional group analysis using FT-IR, showed the conformational arrangements of the keratin protein have mostly amides I–III and O[sbnd]H groups in the bioplastic reinforced with microcrystalline cellulose and showed the substantial hydrogen bonding. The scanning electron microscopy analysis suggested the appropriate morphologies without edge, holes and cavities. The X-Ray diffraction analysis suggested the strong crystalline characteristics of synthesized bioplastic. Finally, the thermogravimetric analysis of K-60 and KC-60, showed the greater cross-linking efficiency between cellulose and keratin at higher temperature. Therefore, the results presented the development of keratin-based bioplastics with high structural strength and morphology good crystallinity which can be used in biomedical applications and manufacturing of food containers and others.
AB - In the present study, bioplastic films were developed using the different ratio of keratin extracted from chicken feathers and cellulose. Firstly, bioplastic (K-60) was developed from the keratin, extracted from the chicken feathers using an alkaline agent (NaOH), and mixed with PVA/glycerol to synthesize protein-based bioplastic. Further, microcrystalline cellulose (2%) was used as an additive to K-60 bioplastic to develop an improved bioplastic (KC-60). The results of functional group analysis using FT-IR, showed the conformational arrangements of the keratin protein have mostly amides I–III and O[sbnd]H groups in the bioplastic reinforced with microcrystalline cellulose and showed the substantial hydrogen bonding. The scanning electron microscopy analysis suggested the appropriate morphologies without edge, holes and cavities. The X-Ray diffraction analysis suggested the strong crystalline characteristics of synthesized bioplastic. Finally, the thermogravimetric analysis of K-60 and KC-60, showed the greater cross-linking efficiency between cellulose and keratin at higher temperature. Therefore, the results presented the development of keratin-based bioplastics with high structural strength and morphology good crystallinity which can be used in biomedical applications and manufacturing of food containers and others.
KW - Bioplastic
KW - Chicken feather
KW - Keratin
KW - Microcrystalline cellulose
UR - http://www.scopus.com/inward/record.url?scp=85063598799&partnerID=8YFLogxK
U2 - 10.1016/j.jksus.2019.03.006
DO - 10.1016/j.jksus.2019.03.006
M3 - Journal article
SN - 1018-3647
VL - 32
SP - 853
EP - 857
JO - Journal of King Saud University - Science
JF - Journal of King Saud University - Science
IS - 1
ER -