Importance of alkyl chain-length on the self-assembly of new Ni(qdt) 2 complexes and charge transport properties

  • Xiong Bo Yang
  • , Li Zhou
  • , Long Biao Huang
  • , Jia Ju Xu
  • , Ye Zhou
  • , Su Ting Han
  • , Zong Xiang Xu
  • , Victor C.Y. Lau
  • , Micheal Hon-Wah Lam
  • , Wai Yeung Wong
  • , V. A.L. Roy*
  • *Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

4 Citations (Scopus)

Abstract

A series of ionic complexes composed with ([Ni(qdt)2] 2-) and alkyl substituted asymmetric viologen derivatives (AV +) as cations have been synthesized and characterized. A slight change in the length of the alkyl chain of AV+ alters the cation-anion packing and leads to different charge transport properties of these complexes. Here, we establish a structure-property relationship of Ni(qdt) 2 complexes by structurally modifying the cations.

Original languageEnglish
Pages (from-to)12075-12079
Number of pages5
JournalRSC Advances
Volume3
Issue number30
DOIs
Publication statusPublished - 14 Aug 2013

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