Through the terpolymerization of complex monomers [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2) and [Zn(L)(4-vinyl-Py)Gd(TTA)3] (4) (H2L = N,N′-bis(salicylidene)cyclohexane-1,2-diamine; 4-vinyl-Py = 4-vinyl-pyridine; HTTA = 2-thenoyltrifluoroacetonate) with MMA (MMA = methyl methacrylate) with different Eu3 +/Gd3 + relative contents, the PMMA-supported while Zn2 +[Formula presented]3 +[Formula presented]3 +-containing metallopolymers Poly(2-co-MMA-co-4) with improved physical properties including highly luminous color-purity red-light efficiencies (ФEuL = 65–73%) were obtained, respectively.
Scopus Subject Areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
- Color-purity red-light
- Tris-β-diketonate Zn[Formula presented]-complex
- Zn[Formula presented][Formula presented]-containing metallopolymer