Highly luminous color-purity red-light PMMA-supported Zn2 +[Formula presented]3 +[Formula presented]3 +-containing metallopolymers

Yani He; Lin Liu; Guorui Fu; Xingqiang Lü; Rick W K WONG; Richard A. Jones

doi:10.1016/j.inoche.2016.08.005

Highly luminous color-purity red-light PMMA-supported Zn^2 +[Formula presented]^3 +[Formula presented]^3 +-containing metallopolymers

Yani He, Lin Liu, Guorui Fu, Xingqiang Lü^*, Rick W K WONG, Richard A. Jones

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

4 Citations (Scopus)

Abstract

Through the terpolymerization of complex monomers [Zn(L)(4-vinyl-Py)Eu(TTA)₃] (2) and [Zn(L)(4-vinyl-Py)Gd(TTA)₃] (4) (H₂L = N,N′-bis(salicylidene)cyclohexane-1,2-diamine; 4-vinyl-Py = 4-vinyl-pyridine; HTTA = 2-thenoyltrifluoroacetonate) with MMA (MMA = methyl methacrylate) with different Eu^3 +/Gd^3 + relative contents, the PMMA-supported while Zn^2 +[Formula presented]^3 +[Formula presented]^3 +-containing metallopolymers Poly(2-co-MMA-co-4) with improved physical properties including highly luminous color-purity red-light efficiencies (Ф_Eu^L = 65–73%) were obtained, respectively.

Original language	English
Pages (from-to)	62-64
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	72
DOIs	https://doi.org/10.1016/j.inoche.2016.08.005
Publication status	Published - 1 Oct 2016

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Color-purity red-light
Tris-β-diketonate Zn[Formula presented]-complex
Zn[Formula presented][Formula presented]-containing metallopolymer

Access to Document

10.1016/j.inoche.2016.08.005

Cite this

@article{d2329c75322f47219c5738132e4eec83,

title = "Highly luminous color-purity red-light PMMA-supported Zn2 +[Formula presented]3 +[Formula presented]3 +-containing metallopolymers",

abstract = "Through the terpolymerization of complex monomers [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2) and [Zn(L)(4-vinyl-Py)Gd(TTA)3] (4) (H2L = N,N′-bis(salicylidene)cyclohexane-1,2-diamine; 4-vinyl-Py = 4-vinyl-pyridine; HTTA = 2-thenoyltrifluoroacetonate) with MMA (MMA = methyl methacrylate) with different Eu3 +/Gd3 + relative contents, the PMMA-supported while Zn2 +[Formula presented]3 +[Formula presented]3 +-containing metallopolymers Poly(2-co-MMA-co-4) with improved physical properties including highly luminous color-purity red-light efficiencies (ФEuL = 65–73%) were obtained, respectively.",

keywords = "Color-purity red-light, Tris-β-diketonate Zn[Formula presented]-complex, Zn[Formula presented][Formula presented]-containing metallopolymer",

author = "Yani He and Lin Liu and Guorui Fu and Xingqiang L{\"u} and WONG, {Rick W K} and Jones, {Richard A.}",

note = "Funding Information: This work is funded by the NNSF ( 21373160 , 91222201 , 21173165 ) and the NCET ( 10-0936 ) in P. R. of China. ",

year = "2016",

month = oct,

day = "1",

doi = "10.1016/j.inoche.2016.08.005",

language = "English",

volume = "72",

pages = "62--64",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Highly luminous color-purity red-light PMMA-supported Zn2 +[Formula presented]3 +[Formula presented]3 +-containing metallopolymers

AU - He, Yani

AU - Liu, Lin

AU - Fu, Guorui

AU - Lü, Xingqiang

AU - WONG, Rick W K

AU - Jones, Richard A.

N1 - Funding Information: This work is funded by the NNSF ( 21373160 , 91222201 , 21173165 ) and the NCET ( 10-0936 ) in P. R. of China.

PY - 2016/10/1

Y1 - 2016/10/1

N2 - Through the terpolymerization of complex monomers [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2) and [Zn(L)(4-vinyl-Py)Gd(TTA)3] (4) (H2L = N,N′-bis(salicylidene)cyclohexane-1,2-diamine; 4-vinyl-Py = 4-vinyl-pyridine; HTTA = 2-thenoyltrifluoroacetonate) with MMA (MMA = methyl methacrylate) with different Eu3 +/Gd3 + relative contents, the PMMA-supported while Zn2 +[Formula presented]3 +[Formula presented]3 +-containing metallopolymers Poly(2-co-MMA-co-4) with improved physical properties including highly luminous color-purity red-light efficiencies (ФEuL = 65–73%) were obtained, respectively.

AB - Through the terpolymerization of complex monomers [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2) and [Zn(L)(4-vinyl-Py)Gd(TTA)3] (4) (H2L = N,N′-bis(salicylidene)cyclohexane-1,2-diamine; 4-vinyl-Py = 4-vinyl-pyridine; HTTA = 2-thenoyltrifluoroacetonate) with MMA (MMA = methyl methacrylate) with different Eu3 +/Gd3 + relative contents, the PMMA-supported while Zn2 +[Formula presented]3 +[Formula presented]3 +-containing metallopolymers Poly(2-co-MMA-co-4) with improved physical properties including highly luminous color-purity red-light efficiencies (ФEuL = 65–73%) were obtained, respectively.

KW - Color-purity red-light

KW - Tris-β-diketonate Zn[Formula presented]-complex

KW - Zn[Formula presented][Formula presented]-containing metallopolymer

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U2 - 10.1016/j.inoche.2016.08.005

DO - 10.1016/j.inoche.2016.08.005

M3 - Journal article

AN - SCOPUS:84983288533

SN - 1387-7003

VL - 72

SP - 62

EP - 64

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -