Highly efficient near-infrared (NIR) luminescent tris-β-diketonate Yb3 + complex in solution and in PMMA

Xinyu Zhang; Lin Liu; Chao Yu; Hongyan Li; Guorui Fu; Xingqiang Lü; Rick W K WONG; Richard A. Jones

doi:10.1016/j.inoche.2016.06.006

Highly efficient near-infrared (NIR) luminescent tris-β-diketonate Yb^{3 +} complex in solution and in PMMA

Xinyu Zhang
, Lin Liu
, Chao Yu
, Hongyan Li
, Guorui Fu
, Xingqiang Lü^*
, Rick W K WONG
, Richard A. Jones

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

12 Citations (Scopus)

Abstract

In the series of binary tris-β-diketonate complexes [Ln(L)₃(Phen)] (HL = (Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one; Phen = 1,10-phenanthroline; Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4 or Ln = Gd, 5), the relatively lower ligands-based ³ππ^∗ energy level (18,727 cm^{- 1}) results in the highly efficient NIR luminescence (Φ_Yb^Yb = 1.37% and Φ_Yb^L = 1.06%) of Yb^{3 +}-based 3 in solution and the higher NIR quantum yield (Φ_Yb^Yb = 1.77% and Φ_Yb^L = 1.31%) in PMMA (Poly(methyl methacrylate) besides the improved physical properties.

Original language	English
Pages (from-to)	153-156
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	70
DOIs	https://doi.org/10.1016/j.inoche.2016.06.006
Publication status	Published - 1 Aug 2016

User-Defined Keywords

NIR luminescence in solution or PMMA
Sensitization and energy transfer
Tris-β-diketonate Ln complexes

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10.1016/j.inoche.2016.06.006

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@article{bcdec0bfac124c489b0680adbce65d7f,

title = "Highly efficient near-infrared (NIR) luminescent tris-β-diketonate Yb3 + complex in solution and in PMMA",

abstract = "In the series of binary tris-β-diketonate complexes [Ln(L)3(Phen)] (HL = (Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one; Phen = 1,10-phenanthroline; Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4 or Ln = Gd, 5), the relatively lower ligands-based 3ππ∗ energy level (18,727 cm- 1) results in the highly efficient NIR luminescence (ΦYbYb = 1.37\% and ΦYbL = 1.06\%) of Yb3 +-based 3 in solution and the higher NIR quantum yield (ΦYbYb = 1.77\% and ΦYbL = 1.31\%) in PMMA (Poly(methyl methacrylate) besides the improved physical properties.",

keywords = "NIR luminescence in solution or PMMA, Sensitization and energy transfer, Tris-β-diketonate Ln complexes",

author = "Xinyu Zhang and Lin Liu and Chao Yu and Hongyan Li and Guorui Fu and Xingqiang L{\"u} and WONG, \{Rick W K\} and Jones, \{Richard A.\}",

note = "Funding Information: This work is funded by the NNSF ( 21373160 , 91222201 , 21173165 ) and NCET ( 10-0936 ) in P. R. of China. ",

year = "2016",

month = aug,

day = "1",

doi = "10.1016/j.inoche.2016.06.006",

language = "English",

volume = "70",

pages = "153--156",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Highly efficient near-infrared (NIR) luminescent tris-β-diketonate Yb3 + complex in solution and in PMMA

AU - Zhang, Xinyu

AU - Liu, Lin

AU - Yu, Chao

AU - Li, Hongyan

AU - Fu, Guorui

AU - Lü, Xingqiang

AU - WONG, Rick W K

AU - Jones, Richard A.

N1 - Funding Information: This work is funded by the NNSF ( 21373160 , 91222201 , 21173165 ) and NCET ( 10-0936 ) in P. R. of China.

PY - 2016/8/1

Y1 - 2016/8/1

N2 - In the series of binary tris-β-diketonate complexes [Ln(L)3(Phen)] (HL = (Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one; Phen = 1,10-phenanthroline; Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4 or Ln = Gd, 5), the relatively lower ligands-based 3ππ∗ energy level (18,727 cm- 1) results in the highly efficient NIR luminescence (ΦYbYb = 1.37% and ΦYbL = 1.06%) of Yb3 +-based 3 in solution and the higher NIR quantum yield (ΦYbYb = 1.77% and ΦYbL = 1.31%) in PMMA (Poly(methyl methacrylate) besides the improved physical properties.

AB - In the series of binary tris-β-diketonate complexes [Ln(L)3(Phen)] (HL = (Z)-3-methyl-1-phenyl-4-(2,2,2-trifluoro-1-hydroxyethylidene)-1H-pyrazol-5(4H)-one; Phen = 1,10-phenanthroline; Ln = La, 1; Ln = Nd, 2; Ln = Yb, 3; Ln = Er, 4 or Ln = Gd, 5), the relatively lower ligands-based 3ππ∗ energy level (18,727 cm- 1) results in the highly efficient NIR luminescence (ΦYbYb = 1.37% and ΦYbL = 1.06%) of Yb3 +-based 3 in solution and the higher NIR quantum yield (ΦYbYb = 1.77% and ΦYbL = 1.31%) in PMMA (Poly(methyl methacrylate) besides the improved physical properties.

KW - NIR luminescence in solution or PMMA

KW - Sensitization and energy transfer

KW - Tris-β-diketonate Ln complexes

UR - https://www.scopus.com/pages/publications/84973902477

U2 - 10.1016/j.inoche.2016.06.006

DO - 10.1016/j.inoche.2016.06.006

M3 - Journal article

AN - SCOPUS:84973902477

SN - 1387-7003

VL - 70

SP - 153

EP - 156

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Highly efficient near-infrared (NIR) luminescent tris-β-diketonate Yb^{3 +} complex in solution and in PMMA

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