Highly-efficient blue neutral mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands

Wen Jin Zhang; Zi Xing Zhou; Li Liu; Xin Xin Zhong; Abdullah M. Asiri; Khalid A. Alamry; Fa Bao Li; Nian Yong Zhu; Wai Yeung Wong; Hai Mei Qin

doi:10.1016/j.jlumin.2017.12.064

Highly-efficient blue neutral mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands

Wen Jin Zhang, Zi Xing Zhou, Li Liu^*, Xin Xin Zhong, Abdullah M. Asiri, Khalid A. Alamry, Fa Bao Li, Nian Yong Zhu, Wai Yeung Wong, Hai Mei Qin

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

18 Citations (Scopus)

Abstract

Highly emissive copper halide complexes with a bidentate phosphine ligand have been paid much attention. Here, a series of four-coordinate mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands, [CuX (dpmb)(PPh₃)] (dpmb = 1,2-bis(diphenylphosphino)–4,5-dimethylbenzene, X = I (1), Br (2) and Cl (3)), were synthesized, and their molecular structures and photophysical properties were investigated. These complexes exhibit intense blue emission in the solid state at room temperature and have peak emission wavelengths at 464–479 nm with microsecond lifetimes (τ = 3.5−4.9 μs; Φ = 0.23−0.52). The emission of the complexes 1–3 mainly originates from MLCT, XLCT and intraligand transitions. Three complexes display moderate thermal stability.

Original language	English
Pages (from-to)	425-430
Number of pages	6
Journal	Journal of Luminescence
Volume	196
DOIs	https://doi.org/10.1016/j.jlumin.2017.12.064
Publication status	Published - Apr 2018

Scopus Subject Areas

Biophysics
Biochemistry
Chemistry(all)
Atomic and Molecular Physics, and Optics
Condensed Matter Physics

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@article{4967cc0f20d84fc98e3707180d7d40ad,

title = "Highly-efficient blue neutral mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands",

abstract = "Highly emissive copper halide complexes with a bidentate phosphine ligand have been paid much attention. Here, a series of four-coordinate mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands, [CuX (dpmb)(PPh3)] (dpmb = 1,2-bis(diphenylphosphino)–4,5-dimethylbenzene, X = I (1), Br (2) and Cl (3)), were synthesized, and their molecular structures and photophysical properties were investigated. These complexes exhibit intense blue emission in the solid state at room temperature and have peak emission wavelengths at 464–479 nm with microsecond lifetimes (τ = 3.5−4.9 μs; Φ = 0.23−0.52). The emission of the complexes 1–3 mainly originates from MLCT, XLCT and intraligand transitions. Three complexes display moderate thermal stability.",

author = "Zhang, {Wen Jin} and Zhou, {Zi Xing} and Li Liu and Zhong, {Xin Xin} and Asiri, {Abdullah M.} and Alamry, {Khalid A.} and Li, {Fa Bao} and Zhu, {Nian Yong} and Wong, {Wai Yeung} and Qin, {Hai Mei}",

note = "Funding Information: This work was supported by the National Natural Science Foundation of China [grant number 21671061 ], Natural Science Foundation of Hubei Province of China [grant number 2013CFA087 ] and Hubei Province High-End Talent Training Program. W.-Y.W. acknowledges the financial support from the Areas of Excellence Scheme, University Grants Committee of HKSAR, China ( AoE/P-03/08 ) and the Hong Kong Polytechnic University ( 1-ZE1C ). ",

year = "2018",

month = apr,

doi = "10.1016/j.jlumin.2017.12.064",

language = "English",

volume = "196",

pages = "425--430",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier",

}

TY - JOUR

T1 - Highly-efficient blue neutral mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands

AU - Zhang, Wen Jin

AU - Zhou, Zi Xing

AU - Liu, Li

AU - Zhong, Xin Xin

AU - Asiri, Abdullah M.

AU - Alamry, Khalid A.

AU - Li, Fa Bao

AU - Zhu, Nian Yong

AU - Wong, Wai Yeung

AU - Qin, Hai Mei

N1 - Funding Information: This work was supported by the National Natural Science Foundation of China [grant number 21671061 ], Natural Science Foundation of Hubei Province of China [grant number 2013CFA087 ] and Hubei Province High-End Talent Training Program. W.-Y.W. acknowledges the financial support from the Areas of Excellence Scheme, University Grants Committee of HKSAR, China ( AoE/P-03/08 ) and the Hong Kong Polytechnic University ( 1-ZE1C ).

PY - 2018/4

Y1 - 2018/4

N2 - Highly emissive copper halide complexes with a bidentate phosphine ligand have been paid much attention. Here, a series of four-coordinate mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands, [CuX (dpmb)(PPh3)] (dpmb = 1,2-bis(diphenylphosphino)–4,5-dimethylbenzene, X = I (1), Br (2) and Cl (3)), were synthesized, and their molecular structures and photophysical properties were investigated. These complexes exhibit intense blue emission in the solid state at room temperature and have peak emission wavelengths at 464–479 nm with microsecond lifetimes (τ = 3.5−4.9 μs; Φ = 0.23−0.52). The emission of the complexes 1–3 mainly originates from MLCT, XLCT and intraligand transitions. Three complexes display moderate thermal stability.

AB - Highly emissive copper halide complexes with a bidentate phosphine ligand have been paid much attention. Here, a series of four-coordinate mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands, [CuX (dpmb)(PPh3)] (dpmb = 1,2-bis(diphenylphosphino)–4,5-dimethylbenzene, X = I (1), Br (2) and Cl (3)), were synthesized, and their molecular structures and photophysical properties were investigated. These complexes exhibit intense blue emission in the solid state at room temperature and have peak emission wavelengths at 464–479 nm with microsecond lifetimes (τ = 3.5−4.9 μs; Φ = 0.23−0.52). The emission of the complexes 1–3 mainly originates from MLCT, XLCT and intraligand transitions. Three complexes display moderate thermal stability.

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U2 - 10.1016/j.jlumin.2017.12.064

DO - 10.1016/j.jlumin.2017.12.064

M3 - Journal article

AN - SCOPUS:85040079629

SN - 0022-2313

VL - 196

SP - 425

EP - 430

JO - Journal of Luminescence

JF - Journal of Luminescence

ER -

Highly-efficient blue neutral mononuclear copper(I) halide complexes containing bi- and mono-dentate phosphine ligands

Abstract

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